16913-63-6

Basic information

• Product Name: 4-nitrophenyl dimethyldithiocarbamate
• Synonyms: 4-nitrophenyl dimethyldithiocarbamate;N,N-Dimethyldithiocarbamic acid 4-nitrophenyl ester
• CAS NO: 16913-63-6
• Molecular Formula: C₉H₁₀N₂O₂S₂
• Molecular Weight: 242.3179
• EINECS: 240-962-0
• Mol File: 16913-63-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 369.2°Cat760mmHg
• Flash Point: 177.1°C
• Appearance: /
• Density: 1.36g/cm³
• Vapor Pressure: 1.21E-05mmHg at 25°C
• Refractive Index: 1.663
• PKA: 0.66±0.50(Predicted)
• CAS DataBase Reference: 4-nitrophenyl dimethyldithiocarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-nitrophenyl dimethyldithiocarbamate(16913-63-6)
• EPA Substance Registry System: 4-nitrophenyl dimethyldithiocarbamate(16913-63-6)

Safety Data

• Hazardous Substances Data: 16913-63-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H10N2O2S2/c1-10(2)9(14)15-8-5-3-7(4-6-8)11(12)13/h3-6H,1-2H3

Upstream product

• 100-05-0 4-nitrobenzenediazonium chloride 
• 100-00-5 4-chlorobenzonitrile 
• 128-04-1 sodium dimethyldithiocarbamate 
• 636-98-6 p-nitrobenzene iodide 
• 137-26-8 Thiram 
• 75-15-0 carbon disulfide 
• 456-27-9 4-nitrobenzenediazonium tetrafluoroborate 
• 124-40-3 dimethyl amine 
• 24067-17-2 4-nitrophenylboronic acid 

Downstream Products

• 21969-11-9 1-(4-chlorophenylthio)-4-nitrobenzene 

Relevant articles and documents

Aryldithiocarbamates as thiol alternatives in Cu-catalyzed C(aryl)-S coupling reactions using aryldiazonium tetrafluoroborate salts

An efficient method for the synthesis of unsymmetrical diaryl sulfides has been developed by the C-S cross coupling of aryldithiocarbamates and aryldiazonium salts in the presence of CuI-2,2′-bipyridine and Zn. Aryldithiocarbamate compounds have been used here as thiol substitutes. The protocol shows wide substrate scope and good yields of the products.

Copper-Catalyzed C(sp2)-S Coupling Reactions for the Synthesis of Aryl Dithiocarbamates with Thiuram Disulfide Reagents

An efficient protocol for the copper-catalyzed preparation of aryl dithiocarbamates from aryl iodides and inexpensive, environmentally benign tetraalkylthiuram disulfides was developed. The features of mild reaction conditions, high yields, and broad substrate scope render this new approach synthetically attractive for the preparation of potentially biologically active compounds.