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1754-55-8

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1754-55-8 Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 740, 1986 DOI: 10.1021/jo00355a032Tetrahedron Letters, 12, p. 4741, 1971

Check Digit Verification of cas no

The CAS Registry Mumber 1754-55-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,7,5 and 4 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1754-55:
(6*1)+(5*7)+(4*5)+(3*4)+(2*5)+(1*5)=88
88 % 10 = 8
So 1754-55-8 is a valid CAS Registry Number.
InChI:InChI=1/C12H16O2/c1-5-14-12(13)11-9(3)6-8(2)7-10(11)4/h6-7H,5H2,1-4H3

1754-55-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Ethyl 2,4,6-trimethylbenzoate

1.2 Other means of identification

Product number -
Other names 2,4,6-Trimethylbenzoic Acid Ethyl Ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1754-55-8 SDS

1754-55-8Relevant articles and documents

-

Raber,Gariano

, (1971)

-

Photoinduced Coupling Reaction of Diphenyl(2,4,6-trimethylbenzoyl)phosphine Oxide with Interelement Compounds: Application to the Synthesis of Thio- or Selenophosphinates

Sato, Yuki,Kawaguchi, Shin-Ichi,Nomoto, Akihiro,Ogawa, Akiya

, p. 3558 - 3567 (2017)

Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (TMDPO) is a radical initiator widely used in the field of macromolecular chemistry, but not often applied in synthetic organic chemistry. We have focused on the use of TMDPO as a phosphorus source in reactions with different E - E compounds, where E - E represents a heteroatom-heteroatom bond, under photoirradiation. Interestingly, the cross-coupling reaction between TMDPO and disulfides or diselenides successfully affords thio- or selenophosphinates and thio- or selenoesters, respectively. The synthesis of series of thio- and selenophosphinates by this photoinduced cross-coupling reaction is demonstrated.

Efficient esterification of carboxylic acids and phosphonic acids with trialkyl orthoacetate in ionic liquid

Yoshino, Tomonori,Imori, Satomi,Togo, Hideo

, p. 1309 - 1317 (2007/10/03)

An operationally simple, inexpensive, efficient, and environmentally friendly esterification of various carboxylic acids, phosphonic acids, and phosphinic acids with triethyl orthoacetate or trimethyl orthoacetate under neutral conditions in a typical room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate, was successfully carried out to provide the corresponding ethyl esters or methyl esters in high yields.

A mild esterification process in phosphonium salt ionic liquid

McNulty, James,Cheekoori, Sreedhar,Nair, Jerald J.,Larichev, Vladimir,Capretta, Alfredo,Robertson, Al J.

, p. 3641 - 3644 (2007/10/03)

A general, high yielding procedure is described for the esterification of carboxylic acids through carboxylate alkylation in phosphonium salt ionic liquid.

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