17599-54-1

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 108-86-1 bromobenzene 
• 75-05-8 acetonitrile 
• 917-54-4 methyllithium 
• 100-47-0 benzonitrile 
• 1749-19-5 phenyl(1-phenylethylidene)amine 
• 65482-07-7 1,4-dihydronaphthalen-1-yltrimethylsilane 
• 54380-53-9 cyclohexa-2,5-dien-1-yl(trimethyl)silane 
• 18002-83-0 9-(trimethylsilyl)-9,10-dihydroanthracene 
• 18090-43-2 3,6-bis(trimethylsilyl)cyclohexane-1,4-diene 
• 98-86-2 acetophenone 
• 4039-32-1 lithium hexamethyldisilazane 

Downstream Products

• 118910-28-4 1,2 diphenyl 2 propylamine 
• 1105601-16-8 (2R,3R)-2-amino-3-methoxy-2-phenyl-4-pentene 
• 1105601-04-4 (2R,3R)-2-amino-3-methoxymethoxy-2-phenyl-4-pentene 

Relevant academic research and scientific papers

Direct and transfer hydrosilylation reactions catalyzed by fully or partially fluorinated triarylboranes: A systematic study

The present survey serves several purposes. Selected electron-deficient boron Lewis acids catalyze the release of hydrosilanes from cyclohexa-2,5-dien-1-yl-substituted silanes. The two-step process consists of a hydride abstraction to generate a silicon-s

New approaches to branched β-amino α-hydroxy acids, taxol side-chain analogs

The phenylisothreonine derivatives, taxol side-chain analogs, were synthesized by two routes, one based on the highly stereoselective addition of a phenyl Grignard reagent to the L-threose-derived nitrone 7, and the other using asymmetric α-alkoxyallylation of the ketimine 20 with chiral allyl boron reagents.

Convenient Access to Primary Amines by Employing the Barbier-Type Reaction of N-(Trimethylsilyl)imines Derived from Aromatic and Aliphatic Aldehydes

A new versatile preparation of primary amines via benzylation of aromatic and aliphatic aldimines is described. Sonochemical and traditional methods for generation of the reactive intermediates are compared and contrasted. Competitive reactions were analyzed via free energy relationships to support the proposed alkylative mechanism.