176791-95-0

Basic information

• Product Name: (4R,5S)-1,5-Dimethyl-3-((2R,3S)-3-methyl-aziridine-2-carbonyl)-4-phenyl-imidazolidin-2-one
• Synonyms: (4R,5S)-1,5-Dimethyl-3-((2R,3S)-3-methyl-aziridine-2-carbonyl)-4-phenyl-imidazolidin-2-one
• CAS NO: 176791-95-0
• Molecular Weight: 273.335
• Mol File: 176791-95-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (4R,5S)-1,5-Dimethyl-3-((2R,3S)-3-methyl-aziridine-2-carbonyl)-4-phenyl-imidazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,5S)-1,5-Dimethyl-3-((2R,3S)-3-methyl-aziridine-2-carbonyl)-4-phenyl-imidazolidin-2-one(176791-95-0)
• EPA Substance Registry System: (4R,5S)-1,5-Dimethyl-3-((2R,3S)-3-methyl-aziridine-2-carbonyl)-4-phenyl-imidazolidin-2-one(176791-95-0)

Safety Data

• Hazardous Substances Data: 176791-95-0(Hazardous Substances Data)

Upstream product

• 92841-65-1 (4R,5S)-1,5-dimethyl-4-phenylimidazolidin-2-one 
• 176792-03-3 (4R,5S)-1,5-Dimethyl-4-phenyl-3-((2R,3S)-3-propyl-aziridine-2-carbonyl)-imidazolidin-2-one 
• 139962-44-0 (4S,5R)-1-((E)-Hex-2-enoyl)-3,4-dimethyl-5-phenyl-imidazolidin-2-one 
• 128947-01-3 (4R,5S)-3-[(2E)-2-butenoyl]-1,5-dimethyl-4-phenyl-2-imidazolidinone 

Downstream Products

• 176791-98-3 (4R,5S,2'R,3'S)-1,5-dimethyl-3-(2'-acetamido-3'-acetoxybutyryl)-4-phenylimidazolidin-2-one 
• 176792-02-2 (4S,5R)-1-((2R,3S)-3-Ethyl-aziridine-2-carbonyl)-3,4-dimethyl-5-phenyl-imidazolidin-2-one 
• 139962-51-9 (4R,5S)-1,5-Dimethyl-3-((E)-pent-2-enoyl)-4-phenyl-imidazolidin-2-one 
• 128947-02-4 (4R,5S)-1,5-dimethyl-3-[(2E)-3-phenyl-2-propenoyl]-4-phenyl-2-imidazolidinone 
• 92841-65-1 (4R,5S)-1,5-dimethyl-4-phenylimidazolidin-2-one 
• 197232-54-5 (4R,5S)-1,5-Dimethyl-3-((4R,5S)-5-methyl-2-phenyl-4,5-dihydro-oxazole-4-carbonyl)-4-phenyl-imidazolidin-2-one 
• 197232-62-5 N-[(1R,2S)-1-((4S,5R)-3,4-Dimethyl-2-oxo-5-phenyl-imidazolidine-1-carbonyl)-2-hydroxy-propyl]-acetamide 
• 176791-97-2 (4S,5R)-1-((4R,5S)-2,5-Dimethyl-4,5-dihydro-oxazole-4-carbonyl)-3,4-dimethyl-5-phenyl-imidazolidin-2-one 
• 221374-50-1 (S)-2-Acetylamino-4-methyl-pentanoic acid [(1R,2S)-1-((4S,5R)-3,4-dimethyl-2-oxo-5-phenyl-imidazolidine-1-carbonyl)-2-hydroxy-propyl]-amide 
• 221374-49-8 N-{(S)-1-[(4R,5S)-4-((4S,5R)-3,4-Dimethyl-2-oxo-5-phenyl-imidazolidine-1-carbonyl)-5-methyl-4,5-dihydro-oxazol-2-yl]-3-methyl-butyl}-acetamide 
• 221374-48-7 N-{(S)-1-[(2R,3S)-2-((4S,5R)-3,4-Dimethyl-2-oxo-5-phenyl-imidazolidine-1-carbonyl)-3-methyl-aziridine-1-carbonyl]-3-methyl-butyl}-acetamide 
• 197232-47-6 (4S,5R)-1-((2R,3S)-1-Benzoyl-3-methyl-aziridine-2-carbonyl)-3,4-dimethyl-5-phenyl-imidazolidin-2-one 
• 176896-54-1 benzyl 3(S)-methylaziridine-2(R)-carboxylate 
• 176791-96-1 (4S,5R)-1-((2R,3S)-1-Acetyl-3-methyl-aziridine-2-carbonyl)-3,4-dimethyl-5-phenyl-imidazolidin-2-one 

Relevant articles and documents

Synthesis of enantiomerically pure aziridine-2-imides by cyclization of chiral 3-benzyloxyamino imide enolates

Aziridine-2-imides are prepared both in high yield and high diastereoselectivity from chiral 3'-benzyloxyamino imides 2, 3, and 8 by treatment with triethylamine in the presence of either TiCl4 or AlMe2Cl. 2 and 3 are easily obtained

Asymmetrische Synthese von Alkylaziridin-2-carbonsaeureestern aus chiralen 3'-Benzyloxyaminoimiden

Keywords: Aziridine, Chirale Auxiliare, Cyclisierungen, Enolate