Journal of the Chemical Society - Faraday Transactions p. 3033 - 3040 (1995)
Update date:2022-08-29
Topics:
Atkinson, Roger
Tuazon, Ernesto C.
Kwok, Eric S. C.
Arey, Janet
Aschmann, Sara M.
Bridier, Isabelle
Direct air-sampling atmospheric-pressure ionisation tandem mass spectrometry and FTIR spectroscopy were used to analyse the products of the OH radical- and Cl atom-imitiated reactions of hexamethyldisiloxane, <2H18>hexamethyldisiloxane, tetramethylsilane and trimethylsilylmethanol at room temperature and atmospheric pressure.The data obtained indicate the initial formation of (CH3)3SiOSi(CH3)2OCHO and (CD3)3SiOSi(CD3)2OCDO from hexamethyldisiloxane and <2H18>hexamethyldisiloxane, respectively, and (CH3)3SiOCHO from both tetramethylsilane and trimethylsilylmethanol.
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