19064-14-3

Basic information

• Product Name: RARECHEM AL BI 0212
• Synonyms: RARECHEM AL BI 0212;ETHYL 2,6-DIFLUOROBENZOATE;2,6-Difluorobenzoic acid, ethyl ester
• CAS NO: 19064-14-3
• Molecular Formula: C₉H₈F₂O₂
• Molecular Weight: 186.16
• EINECS: 943-621-0
• Mol File: 19064-14-3.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 228 °C at 760 mmHg
• Flash Point: 89.2 °C
• Appearance: /
• Density: 1.222 g/cm³
• Vapor Pressure: 0.075mmHg at 25°C
• Refractive Index: 1.472
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: RARECHEM AL BI 0212(CAS DataBase Reference)
• NIST Chemistry Reference: RARECHEM AL BI 0212(19064-14-3)
• EPA Substance Registry System: RARECHEM AL BI 0212(19064-14-3)

Safety Data

• Hazardous Substances Data: 19064-14-3(Hazardous Substances Data)

Usage

General Description

RARECHEM AL BI 0212 is a chemical compound primarily used in various industrial applications. The detailed information such as its chemical structure, properties, potential health hazards, or environmental impact is not publicly available as it might be a proprietary chemical. As a general rule, all chemicals should be handled following appropriate safety guidelines to protect workers and the environment. Precautionary information, safe handling, use, storage, and disposal instructions should usually be available on the product's Material Safety Data Sheet (MSDS), provided by the manufacturer or supplier. Regardless of its specific characteristics, this chemical as with all others should be used responsibly.

InChI:InChI=1/C9H8F2O2/c1-2-13-9(12)8-6(10)4-3-5-7(8)11/h3-5H,2H2,1H3

Upstream product

• 64-17-5 ethanol 
• 18063-02-0 2,6-difluorobenzoylchloride 
• 75-89-8 2,2,2-trifluoroethanol 
• 372-18-9 1,3-Difluorobenzene 
• 109-94-4 formic acid ethyl ester 
• 385-00-2 2,6-difluorobenzoic acid 
• 623-49-4 ethyl cyanoformate 

Downstream Products

• 150368-36-8 ethyl 2,6-difluoro-3-nitrobenzoate 
• 1285530-51-9 1-(2,6-difluorophenyl)-2-(pyrid-4-yl)ethanone 
• 1285528-81-5 4-[3-(2,6-difluorophenyl)-1-(propan-2-yl)-1H-pyrazol-4-yl]pyridine 
• 1285528-77-9 4-[5-(2,6-difluorophenyl)-1-(propan-2-yl)-1H-pyrazol-4-yl]pyridine 
• 1285530-49-5 4-[3-(2,6-difluorophenyl)-1H-pyrazol-4-yl]pyridine 
• 1285530-50-8 1-(2,6-difluorophenyl)-3-(dimethylamino)-2-(pyridin-4-yl)prop-2-en-1-one 
• 172935-91-0 2,6-difluorobenzoic hydrazide 
• 193757-24-3 ethyl 2-fluoro-6-[3,4-(methylenedioxy)phenoxy]benzoate 
• 150368-49-3 2-methyl-1-(1-oxopropoxy)propyl-2-butyl-6-ethoxy-3-<<2'-1H-tetrazol-5-yl<1,1'-biphenyl>-4-yl>oxy>-5-quinoxalinecarboxylate 
• 150368-48-2 2-Butyl-6-ethoxy-3-[[2'-(1H-tetrazol-5-yl)[1,1'-biphenyl]-4-yl]oxy]quinoxaline-5-carboxylic acid 
• 150368-38-0 ethyl 1-amino-6-ethoxy-3-nitrobenzoate 
• 150368-37-9 ethyl 2-amino-6-fluoro-3-nitrobenzoate 
• 150368-39-1 ethyl 2,3-diamino-6-ethoxybenzoate 

Relevant articles and documents

Nickel-Catalyzed Esterification of Amides Under Mild Conditions

Abstract: The use of ligands to adjust the catalytic activity of the catalyst for esterification of amides is challenge in organic chemistry. In this paper, Nickel(II)-NHC-catalyzed the esterification reaction between N,N-di-Boc amide and alcohols at room temperature have been demonstrated. The imidazolium salt bearing a hydroxyl functionalized side arm showed high effective catalytic activity in the activation of the amide N–C bond in air atmosphere. Graphic Abstract: [Figure not available: see fulltext.].

Practical and economic lithiations of functionalized arenes and heteroarenes using Cy2NLi in the presence of Mg, Zn or La halides in a continuous flow

The economic amide base lithium dicyclohexylamide (Cy2NLi) allows fast and convenient (40 s, 0°C) in situ trapping flow metalations of a broad range of functionalized arenes, heteroarenes and acrylate derivatives in the presence of various meta

The importance of the ortho effect in the solvolyses of 2,6-difluorobenzoyl chloride

The ortho effect of the chloro substituents in 2,6-dichlorobenzoyl chloride sufficiently hindered attack on the acyl carbon such that an ionization mechanism was observed over the full range of solvents studied. We now compare this behavior with that of 2,6-difluorobenzoyl chloride. The smaller fluoro substituents allow the dominant pathway to be addition-elimination (association-dissociation) in all solvents except those rich in fluoroalcohol, where ionization is dominant. Ranges of operation for both mechanisms had previously been observed for the parent benzoyl chloride but with a wider ionization range than for the 2,6-difluoro derivative. This indicates that, relative to the parent, the electronic destabilizing influence of the fluorines on acyl cation formation outweighs the steric retardation to attack because of the presence of the two ortho-fluorine atoms. An extended (two-term) Grunwald-Winstein equation treatment of the solvolyses of 2,6-difluorobenzoyl chloride is reported. Copyright