19513-91-8

Basic information

• Product Name: [3-(bromomethyl)-3-phenyloxiran-2-yl](phenyl)methanone
• Synonyms: methanone, [3-(bromomethyl)-3-phenyloxiranyl]phenyl-
• CAS NO: 19513-91-8
• Molecular Formula: C₁₆H₁₃BrO₂
• Molecular Weight: 317.1772
• Mol File: 19513-91-8.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 434.2°C at 760 mmHg
• Flash Point: 216.4°C
• Density: 1.453g/cm³
• Vapor Pressure: 9.63E-08mmHg at 25°C
• Refractive Index: 1.626
• CAS DataBase Reference: [3-(bromomethyl)-3-phenyloxiran-2-yl](phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: [3-(bromomethyl)-3-phenyloxiran-2-yl](phenyl)methanone(19513-91-8)
• EPA Substance Registry System: [3-(bromomethyl)-3-phenyloxiran-2-yl](phenyl)methanone(19513-91-8)

Safety Data

• Hazardous Substances Data: 19513-91-8(Hazardous Substances Data)

Usage

General Description

The chemical [3-(bromomethyl)-3-phenyloxiran-2-yl](phenyl)methanone is a compound that contains a oxiran-2-yl group, a phenyl group and a bromomethyl group attached to an oxirane ring. The presence of the oxirane ring suggests that this compound may have reactivity similar to other epoxides. The bromomethyl group indicates that it contains a bromine atom attached to a carbon atom that is in turn attached to a methylene group. The phenyl group is a benzene ring, indicating the presence of aromaticity. Additionally, the presence of the methanone group suggests the presence of a carbonyl group attached to a methyl group. [3-(bromomethyl)-3-phenyloxiran-2-yl](phenyl)methanone's structure suggests it may have potential for applications in organic synthesis or as a building block in the production of other compounds.

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Relevant articles and documents

An efficient and odorless synthesis of thioethers using 2-[Bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides as thiol equivalents

Using 2-[bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides 1 as odorless thiol equivalents, an efficient and odorless synthesis of thioethers has been developed. Promoted by NaOH in EtOH, the cleavage of 1 commences to generate thiolate anions, and the generated thiolate anions then react with halides to give various thioethers in good yield. It is noteworthy that only a very faint odor of thiols can be perceived during both the reaction and the workup. Using 2-[bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides as odorless thiol equivalents, an efficient and odorless synthesis of thioethers has been developed. Promoted by NaOH in EtOH, the cleavage of 2-[bis(alkylthio)methylene] -3-oxo-N-o-tolylbutanamides commences to generate thiolate anions, and the generated thiolate anions then react with halides to give various thioethers in good yield. Copyright

Regioselective reactions of phenacyl bromide with active methylene compounds

The reactivity of phenacyl bromide with active methylene compounds in the presence of alcoholic KOH, BTEAC (PTC), NaOEt and K2CO3 has been studied.

Reaction of α-halo organoindium reagents with carbonyl compounds and electron-deficient alkenes

A variety of α-halo organoindium reagents were prepared in situ from the reaction of gem-dihalo compounds with indium metal, and their reactions with carbonyl compounds and electron-deficient alkenes were examined. The reactions of simple 1,1-diiodoalkanes with indium metal gave no defined products but benzal iodide gave stilbene in a moderate yield. α-Halo organoindium reagents derived from α,α-dibromo carbonyl compounds gave oxiranes and cyclopropanes upon the reactions with aldehydes and alkenes, respectively. 3,3-Dichloropropenes reacted with aldehydes in the presence of indium metal to give the corresponding chlorohydrins and/or homoallylalcohols, depending on the structures of both the dichloropropenes and aldehydes employed.