19647-26-8

Basic information

• Product Name: Benzene, [(1Z)-2-bromo-1-methylethenyl]-
• CAS NO: 19647-26-8
• Molecular Formula: C9H9Br
• Molecular Weight: 197.074
• Mol File: 19647-26-8.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: Benzene, [(1Z)-2-bromo-1-methylethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1Z)-2-bromo-1-methylethenyl]-(19647-26-8)
• EPA Substance Registry System: Benzene, [(1Z)-2-bromo-1-methylethenyl]-(19647-26-8)

Safety Data

• Hazardous Substances Data: 19647-26-8(Hazardous Substances Data)

Upstream product

• 704-80-3 (E)-3-phenyl-2-butenoic acid 
• 31778-29-7 1-bromo-2-phenylpropan-2-ol 
• 1034-49-7 (bromomethyl)triphenyl phosphonium bromide 
• 98-86-2 acetophenone 
• 98-83-9 isopropenylbenzene 
• 704-79-0 3-phenylbut-2-enoic acid 
• 60014-81-5 1,2-dibromo-2-trimethylsilyloxy-prop-2-yl-benzene 
• 98-82-8 Isopropylbenzene 
• 3360-53-0 1-bromo-2-phenyl-1-propene 
• 66775-59-5 PhMeC=CHAlMe₂ 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 99-90-1 para-bromoacetophenone 
• 123848-50-0 1,1-dibromo-2-phenylpropan-2-ol 
• 100-44-7 benzyl chloride 

Downstream Products

• 673-32-5 1-Phenylprop-1-yne 
• 833-81-8 1,2-diphenylpropene 
• 16819-47-9 2,5-diphenylhexa-2,4-diene 
• 40962-69-4 diethyl 2-phenyl-2-methylvinylphosphonate 
• 52392-67-3 (Z)-3-Phenyl-but-2-enoic acid butyl ester 
• 7283-49-0 2,5-diphenyl-hexa-1,5-diene 
• 98-83-9 isopropenylbenzene 
• 704-79-0 (Z)-3-phenylbut-2-enoic acid 
• 704-80-3 (E)-3-phenyl-2-butenoic acid 
• 3360-55-2 β-chloro-α-methylstyrene 
• 16917-31-0 (Z)-(2-chloro-1-methylvinyl)benzene 
• 16917-32-1 (E)-2-chloro-1-methyl-1-phenylethene 
• 112635-43-5 1,3-dibromo-2-phenylprop-1-ene 
• 98-86-2 acetophenone 

Relevant articles and documents

Visible light photocatalytic one pot synthesis of: Z -arylvinyl halides from e -arylvinyl acids with N -halosuccinimide

An efficient visible light photocatalytic strategy to synthesize thermodynamically less stable Z-arylvinyl halides (with up to >99/1 Z/E ratio and 86% yield) was developed. The reaction combined base-mediated halodecarboxylation of E-arylvinyl acids with N-halosuccinimide and visible light Ir-photocatalyzed isomerization of E-arylvinyl halides in a one pot sequential catalytic process. This journal is

Highly selective hydrosilylation of equilibrating allylic azides

The Pt-catalyzed hydrosilylation of equilibrating allylic azides is reported. The reaction provides only one out of four possible hydrosilylation products in good yields and with very high chemoselectivity (alk-1-enevs.alk-2-ene), regioselectivity (linearvs.branched), and excellent functional group tolerance.

Nickel-Catalyzed Reductive Cross-Coupling of Vinyl Bromides with Unactivated Alkyl Halides

The use of pyridine as the sole ligand for the reductive vinylation of unactivated secondary alkyl halides under Ni-catalyzed conditions has been developed. Both alkyl- and aryl-substituted vinyl bromides are suitable, in which alkyl-decorated α-alkenyl bromides resulted in the α-products in good results.