198478-48-7

Basic information

• Product Name: (phenyl)(2-(pyridin-2-yl)phenyl)methanone
• Synonyms: (phenyl)(2-(pyridin-2-yl)phenyl)methanone
• CAS NO: 198478-48-7
• Molecular Weight: 259.307
• Mol File: 198478-48-7.mol
• Article Data: 38

Chemical Properties

• CAS DataBase Reference: (phenyl)(2-(pyridin-2-yl)phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (phenyl)(2-(pyridin-2-yl)phenyl)methanone(198478-48-7)
• EPA Substance Registry System: (phenyl)(2-(pyridin-2-yl)phenyl)methanone(198478-48-7)

Safety Data

• Hazardous Substances Data: 198478-48-7(Hazardous Substances Data)

Upstream product

• 1008-89-5 2-phenylpyridine 
• 74542-54-4 N,N-phenyl-p-toluenesulfonylbenzamide 
• 119-51-7 1-phenyl-1,2-propanedione 2-oxime 
• 93-55-0 1-phenyl-propan-1-one 
• 615-36-1 2-bromoaniline 
• 109-04-6 2-bromo-pyridine 
• 87698-81-5 1‐(2‐bromophenyl)pyrrolidine 
• 90944-48-2 2-bromo-N,N-diethylaniline 
• 698-00-0 2-bromo-N,N-dimethylaniline 
• 1221640-33-0 N,N-dimethyl-2-(pyridin-2-yl)aniline 
• 201230-82-2 carbon monoxide 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 
• 143-66-8 sodium tetraphenyl borate 

Downstream Products

• 1008-89-5 2-phenylpyridine 
• 219843-48-8 2-(biphenyl-2-yl)pyridine 
• 100-52-7 benzaldehyde 
• 1418179-24-4 C₂₃H₂₀N₂O₃S 
• 1334336-15-0 α-phenyl-(4-phenyl-2-(pyridin-2-yl))benzyl alcohol 
• 1418179-10-8 C₃₁H₂₆N₂O₂S 
• 1334336-26-3 C₂₄H₁₇NO 
• 1334336-75-2 (E,E)-2-(2-(4-methylstyryl)-6-styrylphenyl)pyridine 

Relevant articles and documents

Replacing Pd(OAc)2 with supported palladium nanoparticles in ortho-directed CDC reactions of alkylbenzenes

Supported palladium nanoparticles are used as efficient catalysts for the synthesis of aromatic ketones via cross dehydrogenative coupling reactions of 2-arylpyridines with alkylbenzenes. The catalyst can be reused for five cycles without significantly losing activity. Mechanism research showed that alkylbenzenes were oxidized to their corresponding aldehydes and subsequently coupled with 2-arylpyridines to generate aryl ketones through a Pd0/PdII/PdIV catalytic cycle.

Reaction of organolithium reagents with cyclorhenated and cyclomanganated (η6-arene)tricarbonylchromium complexes: Structural characterization of a new benzoylrhenate intermediate and selective ortho-acetylation of (η6-arene)tricarbonylchromium complexes

The nucleophilic addition of PhLi to tetracarbonyl[3-methyl-2-{(η 6-phenyl)tricarbonylchromium-(0)}pyridine]rhenium(I) yields the air-stable (exo-benzoyl)(tricarbonyl)[3-methyl-2-{(η 6-phenyl)tricarbonylchromium(0)-κC 2′}pyridine-κN]rhenate(I) that has been isolated and characterized by X-ray diffraction analysis and other spectroscopic methods. A similar treatment applied to cyclomanganated (η6-arene)Cr(CO)3 analogues with a nucleophile such as MeLi provides a new route to the synthesis of ortho disubstituted (η6-acetophenone)Cr(CO)3 derivatives.

Acylation of Arenes with Aldehydes through Dual C-H Activations by Merging Photocatalysis and Palladium Catalysis

An acylation of arenes with aldehydes through dual C-H activations at room temperature is reported. The acylation was initiated by phenanthraquinone-catalyzed hydrogen atom transfer from aldehyde under visible light irradiation. The aldehyde-derived acyl

A Strategy for Amide C-N Bond Activation with Ruthenium Catalyst: Selective Aromatic Acylation

A strategy for amide C-N bond activation with ruthenium catalyst is described for the first time. The in situ formed bis-cycloruthenated complexes were demonstrated to be the key active species with superior oxidative addition ability to an inert amide C-N bond. The direct C-H bond activation of 2-arylpyridines followed by the amide C-N bond activation took place in the presence of a ruthenium precatalyst to produce monoacylation products in moderate to good yields. Synthetically useful functional groups, such as halogen atoms (F and Cl), ester, acetyl, and vinyl, remained intact during tandem C-H/C-N bond activation reactions.