2039-77-2 Usage
Description
9-Acetylphenanthrene is an organic chemical compound characterized by a phenanthrene core structure with an acetyl functional group attached to one of its carbon atoms. It is a polycyclic aromatic hydrocarbon known for its potential applications in organic synthesis, pharmaceuticals, and materials science. 9-ACETYLPHENANTHRENE is recognized for its role as a building block in the synthesis of various organic compounds and is also of interest for its potential biological activities, including its study as a potential anticancer agent. Additionally, 9-Acetylphenanthrene serves as a reference standard in analytical chemistry for detecting and quantifying similar polycyclic aromatic compounds in environmental and biological samples.
Uses
Used in Organic Synthesis:
9-Acetylphenanthrene is used as a key building block for the synthesis of a variety of organic compounds. Its unique structure allows for the creation of complex molecules that are valuable in different chemical and pharmaceutical applications.
Used in Pharmaceutical Research:
In the pharmaceutical industry, 9-Acetylphenanthrene is studied for its potential biological activities, particularly as a potential anticancer agent. Its structure may contribute to the development of new drugs targeting cancer cells.
Used in Materials Science:
9-Acetylphenanthrene also finds use in materials science, where its chemical properties can be leveraged to develop new materials with specific characteristics for various applications.
Used as a Reference Standard in Analytical Chemistry:
9-Acetylphenanthrene is utilized as a reference standard for the detection and quantification of similar polycyclic aromatic compounds. This is crucial in environmental and biological studies to assess the presence and impact of these compounds in samples.
Check Digit Verification of cas no
The CAS Registry Mumber 2039-77-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,0,3 and 9 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 2039-77:
(6*2)+(5*0)+(4*3)+(3*9)+(2*7)+(1*7)=72
72 % 10 = 2
So 2039-77-2 is a valid CAS Registry Number.
InChI:InChI=1/C16H12O/c1-11(17)16-10-12-6-2-3-7-13(12)14-8-4-5-9-15(14)16/h2-10H,1H3
2039-77-2Relevant articles and documents
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Bachmann,Struve
, (1940)
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Concise Synthesis of Polysubstituted Carbohelicenes by a C?H Activation/Radical Reaction/C?H Activation Sequence
Yin, Jiangliang,You, Jingsong
, p. 302 - 306 (2019)
Disclosed herein is the merging of C?H activation and radical chemistry, enabling rapid access to a structurally diverse family of fused carbohelicenes through the fusion of α-acetylnaphthalenes with alkynes under oxidative conditions. This cascade process exhibits exquisite chemoselectivity and regioselectivity. The reaction pathway was analyzed by intermediate separations, control experiments, radical trapping, EPR, MALDI-TOF-MS, and ESI-HRMS experiments, and shown to involve a C2?H activation/radical reaction/C8?H activation relay.
Hydration of aromatic alkynes catalyzed by a self-assembled hexameric organic capsule
La Sorella, Giorgio,Sperni, Laura,Ballester, Pablo,Strukul, Giorgio,Scarso, Alessandro
, p. 6031 - 6036 (2016/08/05)
The combination of a Br?nsted acid catalyst and a supramolecular organic capsule formed by the self-assembly of six resorcin[4]arene units efficiently promotes the mild hydration of aromatic alkynes to their corresponding ketones. The capsule provides a suitable nanoenvironment that favors protonation of the substrate and addition of water.
Direct one-pot synthesis of phenanthrenes via Suzuki-Miyaura coupling/aldol condensation cascade reaction
Young, Ha Kim,Lee, Hyuk,Yeong, Joon Kim,Bum, Tae Kim,Heo, Jung-Nyoung
, p. 495 - 501 (2008/09/17)
(Chemical Equation Presented) We have developed an efficient cascade reaction, a Suzuki-Miyaura coupling followed by an aldol condensation, for the construction of phenanthrene derivatives using microwave irradiation. For example, the reaction of methyl 2-bromophenylacetamide with 2- formylphenylboronic acid in the presence of a palladium catalyst and a base provided a biaryl intermediate, which underwent in situ cyclization to afford the corresponding phenanthrene in high yield.