97455-12-4

Upstream product

• 20834-02-0 cis-2,6-diphenylcyclohexanone 
• 817628-42-5 (Z)-dimethyl(phenyl)(5-phenylpent-1-en-1-yl)silane 
• 591-50-4 iodobenzene 
• 1841512-58-0 1,3-dioxoisoindolin-2-yl 4-phenylbutanoate 
• 536-74-3 phenylacetylene 
• 100-52-7 benzaldehyde 
• 52565-60-3 4-phenylbutanoic peroxyanhydride 
• 637-59-2 1-Bromo-3-phenylpropane 
• 100-42-5 styrene 
• 184577-92-2 dimethylphenyl-(5-phenylpent-1-ynyl)silane 
• 1823-14-9 5-phenyl-1-pentyne 

Relevant academic research and scientific papers

Hydroalkylation of terminal aryl alkynes with alkyl diacyl peroxides

A photo and nickel co-catalyzed hydroalkylation of terminal aryl alkynes enabled Z-preferred olefin synthesis has been developed under mild conditions. Alkyl diacyl peroxides were utilized as a new type of alkylation reagents and afforded Z-olefins as the major products in moderate to good yields.

Alkene homologation: via visible light promoted hydrophosphination using triphenylphosphonium triflate

A hydrophosphination reaction of alkenes with triphenylphosphonium triflate under photocatalytic conditions is described. The reaction is promoted by naphthalene-fused N-acylbenzimidazole and is believed to proceed through intermediate formation of a phosphinyl radical cation. The resulting phosphonium salts are directly involved in the Wittig reaction leading to homologated alkenes.

Method for synthesizing cis-olefin by catalyzing decarboxylation coupling reaction of NHP ester and aryl-terminated alkyne with iridium

The invention provides a method for synthesizing Z-selective olefin by catalyzing a decarboxylation coupling reaction of an NHP ester and aryl-terminated alkyne with iridium. The aryl-terminated alkyne and its derivative and the NHP ester undergo a one-po

Stereospecific Ni-catalyzed cross-coupling of potassium alkenyltrifluoroborates with alkyl halides

A general method for the alkenylation of alkyl electrophiles using nearly stoichiometric amounts of the air- and moisture-stable potassium organotrifluoroborates has been developed. Various functional groups were tolerated on both the nucleophilic and electrophilic partner. Reactions of highly substituted E- and Z-alkenyltrifluoroborates, as well as vinyl- and propenyltrifluoroborates, were successful, and no loss of stereochemistry or regiochemistry was observed.

Palladium-catalyzed intermolecular Heck reaction of alkyl halides

Intermolecular Heck reaction of common alkyl halides, a longstanding problem in palladium catalysis, is realized with a simple Pd/dppf catalyst. Both primary and secondary alkyl halides are suitable for coupling with aromatic olefins. Single electron transfer from (dppf)Pd0 to alkyl halide initiated the catalytic cycle and gave alkyl radicals. This journal is the Partner Organisations 2014.

Vinyldimethylphenylsilanes as safety catch silanols in fluoride-free palladium-catalyzed cross-coupling reactions

A series of five structurally diverse vinyldimethylphenylsilanes have been shown to undergo a fluoride-free one-pot palladium-catalyzed cross-coupling reaction with phenyl iodide to give ipso coupled products in 62-86% yield. The limitations of this present protocol lie in the activation of Si-Ph vs protodesilylation by KOTMS/18-C-6, which seems sensitive to the sterics of cis substituents, but not geminal substituents.

Intramolecular Reactions of 1,5-Diaryl-1,5-pentadiyl Radicals

Photochemical decomposition of 2,6-diarylcyclohexanones 1a-d yields 1,2-diarylcyclopentanes 4 and 1,5-diaryl-1-pentenes 5 by intramolecular reaction of the intermediate 1,5-diaryl-1,5-pentadiyls 3.The two stereoisomers cis-4 and trans-4 are formed in equa