2125-35-1Relevant articles and documents
Atom transfer radical addition (ATRA) of carbon tetrachloride and chlorinated esters to various olefins catalyzed by Cp′Ru(PPh 3)(PR3)Cl complexes
Nair, Radhika P.,Pineda-Lanorio, Jocelyn A.,Frost, Brian J.
, p. 96 - 103 (2012)
CpRu(PPh3)(PR3)Cl complexes, where PR 3 = PMe3, PPh3, or PTA (PTA = 1,3,5-triaza-7-phosphaadamantane), were used to catalyze the atom transfer radical addition of chlorinated esters (CClsu
Exploring the substrate scope of the Ru(II)-catalyzed kharasch reaction
Mume, Eskender,Munslow, Ian J.,Kaellstroem, Klas,Andersson, Pher G.
, p. 1005 - 1013 (2008/09/21)
The Kharasch reaction, or atom-transfer addition of polyhalogenated alkanes to alkenes is known to be catalyzed by a number of Ru(II) complexes. The easily prepared [RuCl2(PPh3)3] was used to investigate the reaction scope. A number of halogenated alkanes were added to a range of alkenes with good to excellent regioselectivities.