2132-64-1

Upstream product

• 4356-69-8 1,1-bis-(4-methoxyphenyl)ethylene 
• 600-31-7 2-bromomalonic acid 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 75-25-2 Bromoform 
• 90-96-0 bis(p-methoxyphenyl)methanone 
• 100-66-3 methoxybenzene 
• 2132-68-5 1,1-bis(4-methoxyphenyl)-2,2-dibromoethylene 
• 7726-95-6 bromine 
• 127-09-3 sodium acetate 
• 64-19-7 acetic acid 
• 98921-98-3 1,1-dimethoxy-2-bromoethylene 
• 7388-29-6 1,1-dibromo-2,2-bis-(4-methoxy-phenyl)-ethane 

Downstream Products

• 111936-99-3 7-methoxy-4-(4-methoxy-phenyl)-naphthalene-1,2-dicarboxylic acid-anhydride 
• 75057-06-6 1,1-bis-(4-isopropoxy-phenyl)-4,4-bis-(4-methoxy-phenyl)-buta-1,3-diene 
• 54655-89-9 1,1,4,4-tetrakis(4-methoxyphenyl)butadiene 
• 103510-05-0 1,1-bis-(4-butoxy-phenyl)-4,4-bis-(4-methoxy-phenyl)-buta-1,3-diene 
• 2132-62-9 4,4'-dimethoxydiphenylacetylene 
• 3669-46-3 1-(4-hydroxyphenyl)-2-(4-methoxyphenyl)ethanone 
• 2132-68-5 1,1-bis(4-methoxyphenyl)-2,2-dibromoethylene 
• 4356-69-8 1,1-bis-(4-methoxyphenyl)ethylene 
• 120-44-5 1,4-di(4-methoxyphenyl)ethanone 
• 36697-31-1 2,2-bis-(p-methoxyphenyl)-1-nitroethylene 
• 18523-10-9 1,1-Di--2-phenylthio-aethylen 
• 90-96-0 bis(p-methoxyphenyl)methanone 
• 30860-08-3 4,4'-(1-bromoethene-1,2-diyl)bis(methoxybenzene) 
• 30860-09-4 (Z)-4,4'-(1-bromoethene-1,2-diyl)bis(methoxybenzene) 

Relevant academic research and scientific papers

Synthesis of substituted aryl enol ethers

A facile route toward substituted aryl diarylvinyl ethers 4 is developed from CuI-mediated cross-coupling reaction of substituted phenols 2 with diarylvinyl bromides 3 in the presence of various bidentate-based ligands in DMF. Skeleton 3 is prepared by Yan's bromomethylenation of diarylketones 1 with CHBr3-TiCl4-Mg in the co-solvent of DME and CH2Cl2. The synthetic route obtains moderate yields from the one-step operation and the key structure of 4k is confirmed by X-ray crystallographic analysis. The CADD docking experiments of 4k have been included.

A search for unambiguous vinylic SRN1 reactions

In a search for unambiguous examples of the vinylic SRN1 route, vinyl bromides Ph(CH3)C=CHBr (10), Ph2C=CHBr (15), An2C=C(Br)An (18) and An2C=CBr2 (20) were treated with Me3CCOCH2- under photostimulation conditions in Me2SO, whereas substrates PhCH=CHBr (2), Ph2C=C(Br)Ph (3), 10 and 15 were similarly allowed to react with PhS- and PhCH2S-. With the strongly basic enolate ion, the prevailing reactions were elimination/addition routes, α-deprotonation followed by 1,2-Ph shift and bromide ion elimination, or halophilic steps. With 18, however, an SRN1 route was obtained. The weakly basic but reducing anion PhS- gave the SRN1 route with 2, 3 and 15. The nucleophilic character of the PhCH2S- anion instead prevailed with 15, whereas with 3 a variety of behaviours was obtained. The mechanistic interpretations were supported by the electrochemically determined redox potentials of the substrates. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.

CARBONYL-YLIDE ALS ZWISCHENSTUFEN DER PHOTOREAKTION AROMATISCHER KETONE MIT HALOGENKETENACETALEN

Photoreactions of benzophenones 1 with haloketene acetals 2 yield oxetanes 3 and tetrahydrofuran carboxylic esters 5 as major products.A mechanism with the intermediate formation of 1,4-diradicals and carbonyl ylides is discussed.

Reaction of Olefins with Malonic Acid Derivatives in the Presence of Manganese(III) Acetate

The reaction of methylmalonic acid with mono- and disubstituted olefins in the presence of manganese(III) acetate yielded 2-carboxy-2-methyl-4-butanolides in moderate to good yields.The reactions of bromomalonic acid and chloromalonic acid with a variety