2186-29-0

Basic information

• Product Name: 1,1-diphenylethyl hydroperoxide
• Synonyms: 1,1-Diphenylethyl hydroperoxide; Hydroperoxide, 1,1-diphenylethyl-
• CAS NO: 2186-29-0
• Molecular Formula: C₁₄H₁₄O₂
• Molecular Weight: 214.2598
• Mol File: 2186-29-0.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 370.9°C at 760 mmHg
• Flash Point: 178.1°C
• Density: 1.127g/cm³
• Vapor Pressure: 3.7E-06mmHg at 25°C
• Refractive Index: 1.577
• CAS DataBase Reference: 1,1-diphenylethyl hydroperoxide(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-diphenylethyl hydroperoxide(2186-29-0)
• EPA Substance Registry System: 1,1-diphenylethyl hydroperoxide(2186-29-0)

Safety Data

• Hazardous Substances Data: 2186-29-0(Hazardous Substances Data)

Upstream product

• 612-00-0 1,1'-ethylidenebis-benzene 
• 599-67-7 1,1-diphenylethanol 
• 10496-82-9 2,2,3,3-tetraphenylbutane 
• 108-90-7 chlorobenzene 
• 65-85-0 benzoic acid 
• 87-66-1 2-hydroxyresorcinol 

Downstream Products

• 599-67-7 1,1-diphenylethanol 
• 71-43-2 benzene 
• 108-95-2 phenol 
• 71-36-3 butan-1-ol 
• 73895-30-4 (C₄H₉O)B(C₅H₁₁)(OC₅H₁₁) 
• 109-66-0 pentane 
• 597-52-4 Triethylsilanol 
• 93-99-2 benzoic acid phenyl ester 
• 21726-35-2 1,1-diphenylethyl peroxide 
• 98-86-2 acetophenone 
• 106-51-4 p-benzoquinone 
• 1739-18-0 [18O]phenol 
• 73007-56-4 <18O>acetophenone 
• 530-48-3 1,1-Diphenylethylene 

Relevant articles and documents

Selective one-pot synthesis of various phenols from diarylethanes

Various substituted phenols were selectively synthesized by a one-pot reaction through the NHPI-catalyzed aerobic oxidation of 1,1-diarylethanes followed by treatment with dilute sulfuric acid. The Royal Society of Chemistry.

Titanium(IV) tert-butoxide-tert-butyl hydroperoxide system as oxidant for C-H bonds in hydrocarbons and oxygen-containing compounds

The system Ti(IV) tetra-tert-butoxide-tert-butyl hydroperoxide in mild conditions (20°C) oxidizes C-H bonds of methyl (toluene), methylene (hexane, ethylbenzene, benzyl ethyl ether), and methine (1, 1-diphenylethane, triphenylmethane) groups. The role of oxidant is played by the oxygen generated by the system. The process involves free radicals and produces hydroperoxides and Ti(IV) peroxides. The latter decompose both with preservation and decomposition of the hydrocarbon skeleton. 2005 Pleiades Publishing, Inc.