10496-82-9Relevant articles and documents
Cobalamin-Catalysed Chemical Reactions: Probing the Role of the Nucleotide Loop
Karczewski, Maksymilian,Ociepa, Micha?,Gryko, Dorota
, p. 469 - 477 (2019)
The nucleotide loop in the vitamin B12 structure affects its biological and physicochemical properties, but its role in cobalamin-catalysed reactions still remains disputable. Herein, we show the synthesis of a series of model compounds includi
Photodriven Dehydrogenative Homocoupling of Benzylic C-H Bonds Forming Strained C-C Bonds
Ishida, Naoki,Son, Mingon,Kawasaki, Tairin,Ito, Misato,Murakami, Masahiro
supporting information, p. 2067 - 2070 (2021/10/14)
A photoinduced dehydrogenative homocoupling reaction of alkylarenes is reported. Gaseous hydrogen is evolved as the sole byproduct and neither oxidants nor hydrogen acceptors are required. The present reaction offers an environmentally benign and atom-economical means for forming sterically strained C-C single bonds. It also gives a remarkable example of photodriven reactions overcoming a considerable rise in energy.
Nitrous oxide reduction-coupled alkene-alkene coupling catalysed by metalloporphyrins
Saito, Shunsuke,Ohtake, Hiro,Umezawa, Naoki,Kobayashi, Yuko,Kato, Nobuki,Hirobe, Masaaki,Higuchi, Tsunehiko
supporting information, p. 8979 - 8981 (2013/09/24)
Porphyrin complexes of iron, manganese and cobalt catalysed reductive dimerization of alkenes with NaBH4 under N2O. The reaction system using FeIII porphyrin generated an FeI porphyrin intermediate that reduced N2O to regenerate FeIII porphyrin.
