22198-55-6Relevant academic research and scientific papers
Catalyst-directed guidance of sulfur-substituted enediolates to stereoselective carbon-carbon bond formation with aldehydes
Uraguchi, Daisuke,Yamada, Kohei,Sato, Makoto,Ooi, Takashi
, p. 5110 - 5117 (2018)
A highly chemo-, regio-, and stereoselective glycolate aldol reaction of sulfur-substituted enediolates with aldehydes was developed by employing a l-cyclohexylglycine-derived chiral iminophosphorane as a catalyst. The key for establishing this protocol i
Enantioselective organocatalytic rearrangement of α-acyloxy- β-keto sulfides to α-acyloxy thioesters
Capitta, Francesca,Frongia, Angelo,Piras, Pier Paolo,Pitzanti, Patrizia,Secci, Francesco
experimental part, p. 2955 - 2960 (2011/02/22)
The first highly enantioselective organocatalytic rearrangement of α-acyloxy-β-keto sulfides to α-acyloxy thioesters has been developed which provides a number of important synthetic building blocks in high yield and with excellent enantioselectivities (e
