2239-92-1

Usage

Uses

Used in Agricultural Industry:
Isopropyl N-4-chlorophenylcarbamate is used as an insecticide for protecting crops from a wide range of pests, ensuring higher crop yields and quality.
Used in Residential Applications:
Isopropyl N-4-chlorophenylcarbamate is used as a pesticide in residential settings to control and prevent infestations of insects, mites, and other pests, thereby safeguarding homes and gardens from damage.
It is crucial to handle isopropyl N-4-chlorophenylcarbamate with care, as it can be toxic to humans and other non-target organisms if not used according to safety guidelines. Proper application and adherence to safety measures are essential to minimize potential risks.

Upstream product

• 100-42-5 styrene 
• 780-21-2 N-(4-chlorobenzylidene)aniline 
• 107-13-1 acrylonitrile 
• 2617-79-0 N-(4-chlorophenyl)formamide 
• 67-63-0 isopropyl alcohol 
• 590-28-3 potassium cyanate 
• 106-39-8 bromochlorobenzene 
• 2446-83-5 di-isopropyl azodicarboxylate 
• 106-47-8 4-chloro-aniline 
• 764-42-1 1,2-Dicyanoethylene 
• 292638-85-8 acrylic acid methyl ester 
• 100-00-5 4-chlorobenzonitrile 
• 104-12-1 p-chlorphenylisocyanate 
• 105-64-6 diisopropyl peroxydicarbonate 

Downstream Products

• 39073-70-6 Chloromethyl-(4-chloro-phenyl)-carbamic acid isopropyl ester 
• 109846-61-9 (4-chloro-phenyl)-μ-imido-dicarbonic acid diisopropyl ester 

Relevant academic research and scientific papers

PRODUCTION METHOD FOR AMIDATE COMPOUND

A method for producing an amidate compound represented by Formula (3), comprising reacting a urethane compound represented by Formula (1) with a carboxylate compound represented by Formula (2): (in the formulas, A, n, R1, R2, R3, R4, R5, R6, X, and a are as described in the Description).

Amidate compound, catalyst for polyurethane production, and method for producing polyurethane resin

Provided is an amidate compound represented by the formula (1): wherein A is a substituted or unsubstituted hydrocarbon group, n is an integer of 1 or more, and D is a nitrogen-containing organic group represented by the formula (2): wherein R1, R2, and R3 are the same or different, and are each a hydrocarbon group that may contain a heteroatom; some or all of R1, R2, and R3 may be bonded together to form a ring structure; X is a nitrogen atom, an oxygen atom, or a sulfur atom; and a is 0 or 1, wherein a is 1 when X is a nitrogen atom, and a is 0 when X is an oxygen atom or a sulfur atom.

METHOD FOR PRODUCING CARBAMATE

PROBLEM TO BE SOLVED: To provide a method for producing carbamate in which a high yield can be obtained and the amount of by-products produced can be reduced. SOLUTION: In the method, carbamate is synthesized using at least one member selected from the group consisting of amine and derivative thereof, alcohol having 3 or more carbon atoms and carbon dioxide as a raw material, cerium oxide as a catalyst, and 2-cyanopyridine as a dehydrating agent. By using an alcohol having 3 or more carbon atoms, a high yield can be obtained and the amount of by-products produced can be reduced. In addition, the pressure of carbon dioxide can be lowered and the production can be of ease. SELECTED DRAWING: Figure 1 COPYRIGHT: (C)2018,JPO&INPIT

Copper-catalyzed carbonylation of anilines by diisopropyl azodicarboxylate for the synthesis of carbamates

A Cu-catalyzed efficient methodology for the direct carbonylation of anilines has been developed. The N-H bond cleavage and N-C bond formation were notably achieved under solvent-free conditions and a variety of carbamates were synthesized from readily available anilines using diisopropyl azodicarboxylate (DIAD) as the carbonylating source.

Synthesis of aryl carbamates via copper-catalyzed coupling of aryl halides with potassium cyanate

Coupling of aryl halides with potassium cyanate takes place at 100-110 °C in alcohols under the catalysis of CuI (cuprous iodide) and 2-(2,6-dimethylphenylamino)-2-oxoacetic acid, affording the corresponding aryl carbamates with great diversity. Copyright

THE REACTION OF IMIDOYL RADICALS WITH MULTIPLE CARBON-CARBON BONDS

A general view on the reaction between imidoyl radicals and carbon-carbon double or triple bonds is given; the synthesis of substituted quinolines starting from imines and alkenes is described, pointing out the differences with respect to the analogous reaction performed with alkynes.

Reduction of Nitroarenes to Anilines in Basic Alcoholic Media

Substituted nitrobenzenes are reduced by alkoxide ions in alcohols to the corresponding azoxy and aniline derivatives.The reaction leading to anilines has been investigated in detail.Two different processes have been identified, both initiated by the condensation between the nitrosoarene intermediate (the first product of the reduction reaction) and the product of oxidation of the solvent.The imino derivative thus formed (ArN=CH-COR) may either undergo hydrolysis (to aniline) or form, through a series of redox processes, compounds containing the ArNH-CO moiety.These are also hydrolysed to anilines in a slower reaction.