22409-85-4

Basic information

• Product Name: 2-Butanone, 4-phenoxy-
• Synonyms: 4-phenoxybutan-2-one;2-Butanone, 4-phenoxy-
• CAS NO: 22409-85-4
• Molecular Formula: C₁₀H₁₂O₂
• Molecular Weight: 164.2
• Mol File: 22409-85-4.mol
• Article Data: 14

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Butanone, 4-phenoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 4-phenoxy-(22409-85-4)
• EPA Substance Registry System: 2-Butanone, 4-phenoxy-(22409-85-4)

Safety Data

• Hazardous Substances Data: 22409-85-4(Hazardous Substances Data)

Upstream product

• 78-94-4 methyl vinyl ketone 
• 108-95-2 phenol 
• 689-97-4 3-buten-1-yne 
• 14503-58-3 3-methylallyloxy benzene 
• 590-90-9 1-Hydroxy-3-butanone 
• 71-43-2 benzene 
• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 2653-89-6 4-phenoxy-1-butene 
• 72024-02-3 (E)-4-phenoxybut-3-en-2-one 

Downstream Products

• 60044-74-8 4-ethoxy-butan-2-one 
• 1206515-44-7 1-(2,5-diphenyl-4,5-dihydrofuran-3-yl)ethanone 
• 1206515-43-6 (2-methyl-5-phenyl-4,5-dihydrofuran-3-yl)(phenyl)methanone 
• 61904-01-6 4-phenoxy-2-butanol 
• 16982-89-1 4-methylchroman 
• 5471-51-2 4-(4-hydroxyphenyl)-2-oxobutane 

Relevant articles and documents

Palladium-catalyzed anti-Markovnikov oxidative acetalization of activated olefins with iron(iii) sulphate as the reoxidant

This paper discloses the efficient palladium-catalyzed anti-Markovnikov oxidative acetalization of activated terminal olefins with iron(iii) sulfate as the reoxidant. This methodology requires mild reaction conditions and shows high regioselectivity toward anti-Markovnikov products and compatibility with a wide range of functional groups. Iron(iii) sulphate was the sole reoxidant used in this method. Various olefins like vinylarenes, aryl-allylethers, aryl or benzyl acrylates and homoallylic alcohols all reacted well providing anti-Markovnikov acetals, some of which represent orthogonally functionalized 1,3- and 1,4-dioxygenated compounds.

Tuning Regioselectivity of Wacker Oxidation in One Catalytic System: Small Change Makes Big Step

A regioselectivity switchable aerobic Wacker-Tsuji oxidation has been developed using catalytic tert-butyl nitrite as a simple organic redox cocatalyst. By solely switching the solvent, either substituted aldehydes or ketones could be prepared under mild

Benzene C-H Etherification via Photocatalytic Hydrogen-Evolution Cross-Coupling Reaction

Aryl ethers can be constructed from the direct coupling between the benzene C-H bond and the alcohol O-H bond with the evolution of hydrogen via the synergistic merger of photocatalysis and cobalt catalysis. Utilizing the dual catalyst system consisting of 3-cyano-1-methylquinolinum photocatalyst and cobaloxime, intermolecular etherification of arenes with various alcohols and intramolecular alkoxylation of 3-phenylpropanols with formation of chromanes are accomplished. These reactions proceed at remarkably mild conditions, and the sole byproduct is equivalent hydrogen gas.