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Bis(dimethyldithiocarbamic acid)methylene ester, with the molecular formula C7H12N2S6, is a yellow to brown crystalline solid. It has a melting point of 108-110°C and is insoluble in water but soluble in organic solvents. This chemical compound is commonly used as a vulcanization accelerator in the rubber industry and as an intermediate in the synthesis of other organic compounds.

22656-77-5

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22656-77-5 Usage

Uses

Used in Rubber Industry:
Bis(dimethyldithiocarbamic acid)methylene ester is used as a vulcanization accelerator for enhancing the process of rubber production. It helps in cross-linking the polymer chains, which improves the rubber's strength, elasticity, and durability.
Used in Chemical Synthesis:
Bis(dimethyldithiocarbamic acid)methylene ester serves as an intermediate in the synthesis of various organic compounds. Its unique structure allows it to be a valuable building block in the creation of different chemical products.
Safety Precautions:
It is important to handle Bis(dimethyldithiocarbamic acid)methylene ester with care, as it is potentially harmful if ingested or inhaled. It can cause irritation to the respiratory system and skin. Following proper safety protocols is essential when working with this chemical compound.

Check Digit Verification of cas no

The CAS Registry Mumber 22656-77-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,2,6,5 and 6 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 22656-77:
(7*2)+(6*2)+(5*6)+(4*5)+(3*6)+(2*7)+(1*7)=115
115 % 10 = 5
So 22656-77-5 is a valid CAS Registry Number.
InChI:InChI=1/C7H14N2S4/c1-8(2)6(10)12-5-13-7(11)9(3)4/h5H2,1-4H3

22656-77-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name dimethylcarbamothioylsulfanylmethyl N,N-dimethylcarbamodithioate

1.2 Other means of identification

Product number -
Other names Bis-(dimethylamino-thiocarbamoylmercapto)-methan

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:22656-77-5 SDS

22656-77-5Relevant academic research and scientific papers

Dynamic NMR studies of a potential chiroptical switch based on dithiocarbamate-iminodithiolane interconversion

Aubin, Lauren B.,Wagner, Tracy M.,Thoburn, John D.,Kesler, Brenda S.,Hutchison, Katherine A.,Schumaker, Robert R.,Parakka, James P.

, p. 3413 - 3416 (2001)

Equation presented Variable temperature NMR spectra of the chiral spiro[(4-N,N-dimethyldithiocarbamato)-(2-N,N-dimethylimino)-1,3-dithiolane-5, 9′-xanthene] show complex dynamics including degenerate interconversion of the dithiocarbamate and iminodithiolane groups. The rate of this switching process can be controlled by chemical modification: the analogous spiro[dithiolane-fluorene] derivative shows no interconversion. These novel materials have potential application as molecular switching elements in information storage devices.

An approach to biologically important S-heterocycles, dithiocarbamyls, and their relevant phosphono derivatives

Khidre, Maha D.,Kamel, Azza A.,Abdou, Wafaa M.

, p. 103 - 108 (2007/10/03)

The feasibility of insertions of carbanions between two sulfur atoms has been reported when 5-(4-chlorophenyl)-4-cyano-1,2-dithiol-3-thione (1) and tetramethylthiuram disulfide (17) were allowed to react with unsaturated 2a,b and active phosphonium salts

Hapten synthesis for the development of a competitive inhibition enzyme-immunoassay for thiram

Gueguen,Boisde,Queffelec,Haelters,Thouvenot,Corbel,Nodet

, p. 4492 - 4499 (2007/10/03)

An enzyme-linked immunosorbent assay (ELISA) was developed for the fungicide thiram. Two types of haptens were synthesized. The first type exhibits the two symmetrical N-alkyl dithiocarbamate patterns of thiram with a spacer arm linked to one of the N-methyl terminal group. The second type exhibits one of the two symmetrical N-alkyl dithiocarbamate patterns of thiram with a variable-length spacer arm linked to one sulfur atom. Polyclonal antibodies suitable for thiram detection were obtained from immunization with an hapten of the first type, while haptens of the second type were used as coating antigens to develop a competitive ELISA against thiram. The IC50 value for thiram was estimated to be 0.24 μg/mL, with a detection limit of 0.03 μg/mL. The assay seems to be thiram-specific since no or little cross-reaction with other dithiocarbamates were observed.

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