2316-85-0

Basic information

• Product Name: 4-Cyclohexylbutane-2-one
• Synonyms: 1-Cyclohexyl-3-butanone;4-Cyclohexyl-2-butanone;4-Cyclohexylbutane-2-one;Methyl 2-cyclohexylethyl ketone;4-cyclohexylbutan-2-one
• CAS NO: 2316-85-0
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.25
• Mol File: 2316-85-0.mol
• Article Data: 42

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-Cyclohexylbutane-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Cyclohexylbutane-2-one(2316-85-0)
• EPA Substance Registry System: 4-Cyclohexylbutane-2-one(2316-85-0)

Safety Data

• Hazardous Substances Data: 2316-85-0(Hazardous Substances Data)

Upstream product

• 10528-67-3 4-cyclohexyl-2-butanol 
• 41437-85-8 (E)-4-cyclohex-1-enyl-but-3-en-2-one 
• 39098-75-4 3-cyclohexylpropionyl chloride 
• 710-07-6 5-Cyclohexyl-3-methyl-pentin-⁽¹⁾-ol-⁽³⁾ 
• 110-82-7 cyclohexane 
• 78-94-4 methyl vinyl ketone 
• 626-62-0 Cyclohexyl iodide 
• 108-85-0 1-bromocyclohexane 
• 67-64-1 acetone 
• 1192-37-6 methylenecyclohexane 
• 100-42-5 styrene 
• 2550-26-7 4-Phenyl-2-butanone 
• 876-27-7 4-chlorophenyl acetate 
• 114180-63-1 (E)-2-(4-cyclohexylbut-3-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Downstream Products

• 113606-76-1 1,2-dimethyl-3-cyclohexylmethylindole 
• 710-07-6 5-Cyclohexyl-3-methyl-pentin-⁽¹⁾-ol-⁽³⁾ 
• 854860-01-8 3-cyclohexylmethyl-2-methyl-quinoline-4-carboxylic acid 
• 868136-06-5 C₂₄H₃₆O₆ 
• 868136-08-7 UTKO₂ 
• 868136-07-6 C₁₁H₁₇F₃O₃S 
• 1326703-73-4 ethyl (3S)-3-[dimethyl(phenyl)silyl]-2-(ethoxycarbonyl)-7-cyclohexyl-5-oxoheptanoate 
• 1326703-76-7 ethyl (3S)-3-[dimethyl(phenyl)silyl]-7-cyclohexyl-5-oxoheptanoate 
• 92037-14-4 5-Cyclohexyl-3-methyl-pent-1-en-3-ol 
• 119948-26-4 <<1-(2-Cyclohexylethyl)-1-methyl-3-butynyl>oxy>trimethylsilane 

Relevant articles and documents

Photochemistry of acetone in the presence of exocyclic olefins: An unexpected competition between the photo-Conia and Paterno-Buechi reactions

When irradiated in the presence of several exocyclic olefins, acetone undergoes homoalkylation with the olefins to form a series of 4-cycloalkylbutan-2-ones (with quantum yields of 0.14 ± 0.01) rather than exhibiting the expected Paterno-Buechi reaction; in contrast, the photolysis of perdeuteriated acetone gave both types of products.

Organometallic Synthesis of Bimetallic Cobalt-Rhodium Nanoparticles in Supported Ionic Liquid Phases (CoxRh100?x@SILP) as Catalysts for the Selective Hydrogenation of Multifunctional Aromatic Substrates

The synthesis, characterization, and catalytic properties of bimetallic cobalt-rhodium nanoparticles of defined Co:Rh ratios immobilized in an imidazolium-based supported ionic liquid phase (CoxRh100?x@SILP) are described. Following an organometallic approach, precise control of the Co:Rh ratios is accomplished. Electron microscopy and X-ray absorption spectroscopy confirm the formation of small, well-dispersed, and homogeneously alloyed zero-valent bimetallic nanoparticles in all investigated materials. Benzylideneacetone and various bicyclic heteroaromatics are used as chemical probes to investigate the hydrogenation performances of the CoxRh100?x@SILP materials. The Co:Rh ratio of the nanoparticles is found to have a critical influence on observed activity and selectivity, with clear synergistic effects arising from the combination of the noble metal and its 3d congener. In particular, the ability of CoxRh100?x@SILP catalysts to hydrogenate 6-membered aromatic rings is found to experience a remarkable sharp switch in a narrow composition range between Co25Rh75 (full ring hydrogenation) and Co30Rh70 (no ring hydrogenation).

Carbonylation of tertiary carbon radicals: synthesis of lactams

Herein, we disclose an interesting iron-catalyzed approach for the carbonylation of a tertiary carbon radical. The tertiary carbon radical generated from a 1,5-hydrogen atom transfer can be captured by CO gas smoothly. Various six-membered lactams were constructed chemo-selectively in high yields.