2437-49-2

Basic information

• Product Name: 2,4,6-TRIBROMORESORCINOL
• Synonyms: 2,4,6-Tribromo-1,3-benzenediol;1,3,5-Tribromo-2,4-dihydroxybenzene;2,4,6-tribromobenzene-1,3-diol;2,4,6-tribromo-resorcino;2,4,6-TRIBROMORESORCINOL;TRIBROMORESORCINOL
• CAS NO: 2437-49-2
• Molecular Formula: C₆H₃Br₃O₂
• Molecular Weight: 346.8
• EINECS: 219-442-2
• Product Categories: Organic Building Blocks;Oxygen Compounds;Polyols;Building Blocks;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds
• Mol File: 2437-49-2.mol
• Article Data: 14

Chemical Properties

• Melting Point: 114-116 °C(lit.)
• Boiling Point: 254.9 °C at 760 mmHg
• Flash Point: 108 °C
• Appearance: /
• Density: 2.571 g/cm³
• Vapor Pressure: 0.0105mmHg at 25°C
• Refractive Index: 1.716
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 5.83±0.28(Predicted)
• CAS DataBase Reference: 2,4,6-TRIBROMORESORCINOL(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-TRIBROMORESORCINOL(2437-49-2)
• EPA Substance Registry System: 2,4,6-TRIBROMORESORCINOL(2437-49-2)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• RTECS: VH3500000
• Hazardous Substances Data: 2437-49-2(Hazardous Substances Data)

Usage

General Description

2,4,6-Tribromoresorcinol was quantified by using five-point calibration curves with data points.

InChI:InChI=1/C6H3Br3O2/c7-2-1-3(8)6(11)4(9)5(2)10/h1,10-11H

Upstream product

• 77-48-5 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione 
• 108-46-3 recorcinol 
• 64-17-5 ethanol 
• 21389-96-8 2,2,4,6,6-pentabromo-cyclohex-4-ene-1,3-dione 
• 89-86-1 4-hydroxysalicylic acid 
• 74131-25-2 4-(1-adamantyl)benzene-1,3-diol 
• 52236-92-7 3-(2,4-dihydroxy-phenyl)-3-phenyl-phthalide 
• 7726-95-6 bromine 
• 7647-01-0 hydrogenchloride 
• 64-19-7 acetic acid 
• 60-29-7 diethyl ether 
• 7732-18-5 water 
• 36942-09-3 N,N-dichlorourea 
• 7664-93-9 sulfuric acid 

Downstream Products

• 484653-22-7 2-bromo-4,6-dinitro-resorcinol 
• 28010-46-0 1,5,5,1',5',5'-hexabromo-[3,3']bicyclohex-1-enylidene-4,6,4',6'-tetraone 
• 108-93-0 cyclohexanol 
• 96337-99-4 2,4-diacetoxy-1,3,5-tribromo-benzene 
• 484653-20-5 2,4-dibromo-6-nitro-resorcinol 
• 18011-67-1 2,4-dibromo-1,3-benzenediol 
• 6751-75-3 2-bromoresorcinol 
• 61524-51-4 2,4-dibromo-5-hydroxyphenol 

Relevant articles and documents

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Electrochemical synthesis of quinones and other derivatives in biphasic medium

Electrochemical synthesis of quinones has been attempted from phenols, 1,4-dihydroxybenzenes, 1,4-dihydroxynaphthalenes and related compounds using biphasic media. Excellent yields of quinones (98%) or brominated diols have been achieved with good current efficiency. Reuse of the electrolyte without any modification and quantitative conversion of substrate with theoretical amount of current are the advantages of this method.

Copper(II)-catalyzed aromatization followed by bromination of cyclohexenones leading to phenols and bromophenols

Conversion of substituted cyclohexenones into the corresponding phenols can be achieved using copper acetate as the catalyst in the presence of LiBr and CF3COOH under oxygen. With the use of excess LiBr, electrophilic aromatic bromination afforded the corresponding bromophenol under similar catalytic conditions. Copyright