24731-36-0Relevant articles and documents
Trimethylsilyl cyanide addition to carbonyl compounds under neutral condition catalyzed by iodine
Azizi, Najmedin,Saidi, Mohammad R.
, p. 2111 - 2115 (2003)
Reaction of trimethylsilyl cyanide with aliphatic or aromatic aldehydes and ketones in the presence of a catalytic amount of elemental iodine produced the corresponding cyanohydrin trimethylsilyl ethers in very short time and high yields.
Solvent-free heterogeneous catalysis for cyanosilylation in a modified sodalite-type Cu(II)-MOF
Zhang, Ling-Juan,Han, Cai-Yun,Dang, Qin-Qin,Wang, Yan-Hong,Zhang, Xian-Ming
, p. 24293 - 24298 (2015)
Solvothermal reaction of Cu(OAc)2 and H3BTT·2HCl generated a sodalite-type metal-organic framework [(Cu4O0.27Cl0.73)3(H0.5BTT)8(H2O)12]·3MeOH·9DM
Determination, par spectrometries infrarouge et Raman, de la stereochimie de cyclohexylcyanhydrines O-trimethylsilylees
Marchand, Annette,Gerval, Pierre,Picard, Jean-Paul
, p. 1735 - 1744 (1991)
A homogeneous series of α-trimethylsiloxynitriles 1-8, obtained by cyanosilylation of cyclohexanones, was investigated by Raman and IR spectroscopies.This study yielded information that complements previous fragmentary NMR results.It was shown that both p
A micro-environment tuning approach for enhancing the catalytic capabilities of lanthanide containing polyoxometalate in the cyanosilylation of ketones
Li, Sang-Hao,Lin, Ming-Yuan,Nie, Yan-Mei,Yan, Jun
, p. 3809 - 3812 (2020)
The as-synthesized (TBA)8H5[Nd(SiW11O39)2] manifested high catalytic activity for cyanosilylation of ketones, and its catalytic activity could be improved further through rational design of the reacti
Synthesis, characterization, crystal structure of magnesium compound based 3, 3′, 5, 5′-azobenzentetracarboxylic acid and application as high-performance heterogeneous catalyst for cyanosilylation
Li, Yong-Peng,Zhang, Ling-Juan,Ji, Wen-Juan
, p. 607 - 614 (2017)
A novel coordination compound with the formula {[H3O]2[Mg(ABTC)(DMI)2]}n (1) (H4ABTC?=?3,3′,5,5′-azobenzene-tetracarboxylic acid, DMI?=?1,3-dimethy-2-imidazolidinone) as synthesized under solvothermal
n-Butyllithium as a highly efficient precatalyst for cyanosilylation of aldehydes and ketones
Kang, Zihan,Wang, Yuhong,Xu, Xiaojuan,Xue, Mingqiang,Zhang, Wenxuan,Zhou, Shuai,Zhu, Xu
supporting information, p. 7432 - 7437 (2021/09/07)
A highly efficient cyanosilylation protocol mediated by the easily availablen-BuLi with a wide range of aldehydes and ketones was developed. This protocol features excellent yields with very lown-BuLi loadings (0.01-0.05 mol%) at room temperature, solvent
Synthesis of cyanooxovanadate and cyanosilylation of ketones
Hayashi, Yoshihito,Kawabata, Hiroko,Kikukawa, Yuji
, p. 31688 - 31692 (2021/11/30)
The cyanosilylation was performed by using metavanadate catalysts, and in situ measurements revealed the formation of [VO2(CN)3]2- and [VO4TMS2]- under reaction conditions. The reaction of [VO2(CN)3]2-, trimethylsilyl cyanide (TMSCN), and water afforded [
