2489-87-4

Basic information

• Product Name: 3-(2-NAPHTHYL)-1-PROPENE
• Synonyms: 3-(2-NAPHTHYL)-1-PROPENE;2-allylnaphthalene
• CAS NO: 2489-87-4
• Molecular Formula: C₁₃H₁₂
• Molecular Weight: 168.23
• Mol File: 2489-87-4.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 276.1°C at 760 mmHg
• Flash Point: 119.5°C
• Appearance: /
• Density: 1.001g/cm³
• Vapor Pressure: 0.00824mmHg at 25°C
• Refractive Index: 1.606
• CAS DataBase Reference: 3-(2-NAPHTHYL)-1-PROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2-NAPHTHYL)-1-PROPENE(2489-87-4)
• EPA Substance Registry System: 3-(2-NAPHTHYL)-1-PROPENE(2489-87-4)

Safety Data

• Hazardous Substances Data: 2489-87-4(Hazardous Substances Data)

Usage

General Description

3-(2-naphthyl)-1-propene is a chemical compound with the chemical formula C15H12. It is an unsaturated hydrocarbon classified as a propene, which means it contains a propene group, characterized by a double bond between the second and third carbon atoms. 3-(2-naphthyl)-1-propene is a derivative of naphthalene, a polycyclic aromatic hydrocarbon, and is commonly used in organic synthesis and as a building block for the production of various chemical compounds. It is also known by the trade name β-naphthyl styrene and is primarily utilized in research and industrial applications. 3-(2-NAPHTHYL)-1-PROPENE may be a potential irritant to the eyes, skin, and respiratory system, and proper handling and safety measures should be taken when working with it.

InChI:InChI=1/C13H12/c1-2-5-11-8-9-12-6-3-4-7-13(12)10-11/h2-4,6-10H,1,5H2

Upstream product

• 53651-72-2 diethyl allylmethylmalonate 
• 580-13-2 2-bromonaphthalene 
• 21473-01-8 2-naphthalenylmagnesium bromide 
• 106-95-6 allyl bromide 
• 32316-92-0 naphthalene-2-boronic acid 
• 1622837-44-8 3-methyl-4-(naphthalen-2-yl)butan-2-one 
• 1145-08-0 naphthalen-2-yl N,N-dimethylsulfamic acid 
• 24850-33-7 allyltributylstanane 
• 591-87-7 Allyl acetate 
• 3857-83-8 2-naphthyl triflate 
• 91-20-3 naphthalene 
• 106-42-3 para-xylene 
• 107-18-6 allyl alcohol 

Downstream Products

• 213617-67-5 (Z)-3-(naphthalen-2-yl)acrylaldehyde 
• 20884-05-3 (E)-3-(2-naphthyl)-2-propenal 
• 1374000-05-1 (1R,4R,5R)-1,4,5-trihydroxy-3-(3-(naphth-2-yl)propyl)cyclohex-2-ene-1-carboxylic acid 
• 1609490-06-3 (E)-2-(3-(perfluorophenyl)prop-1-en-1-yl)naphthalene 
• 145233-31-4 (+/-)-2-hydroxy-3-(2-naphthyl)-1-[1-(4-phenylpiperidinyl)]propane 
• 7726-45-6 5-phenylvaleronitrile 
• 73475-33-9 2-methyl-4-phenylbutanenitrile 
• 15410-83-0 2-(naphthalen-2-yl)butanoic acid 
• 782-28-5 4-(2-naphthyl)butyric acid 
• 107777-19-5 2-methyl-3-naphthalen-2-ylpropionic acid 

Relevant articles and documents

Olefination via Cu-Mediated Dehydroacylation of Unstrained Ketones

The dehydroacylation of ketones to olefins is realized under mild conditions, which exhibits a unique reaction pathway involving aromatization-driven C-C cleavage to remove the acyl moiety, followed by Cu-mediated oxidative elimination to form an alkene between the α and β carbons. The newly adopted N′-methylpicolinohydrazonamide (MPHA) reagent is key to enable efficient cleavage of ketone C-C bonds at room temperature. Diverse alkyl- and aryl-substituted olefins, dienes, and special alkenes are generated with broad functional group tolerance. Strategic applications of this method are also demonstrated.

Nickel-Catalyzed Stille Cross Coupling of C-O Electrophiles

Aryl sulfamates, tosylates, and mesylates undergo efficient Ni-catalyzed cross coupling with diverse organostannanes in the presence of relatively unhindered alkylphosphine ligands and KF. The coupling is valuable for difficult bond constructions, such as aryl - heteroaryl, aryl - alkenyl, and aryl - alkynyl, using nontriflate phenol derivatives. A combination of experimental and computational studies implicates an unusual mechanism for transmetalation involving an 8-centered cyclic transition state. This reaction is inhibited by chloride sources due to slow transmetalation of organostannanes at a Ni(II) - chloride intermediate. These studies help to explain why prior efforts to achieve Ni-catalyzed Stille coupling of phenol derivatives were unsuccessful.

Nickel-catalyzed arylative ring-opening of 3-methylenecycloalkane-1,1- dicarboxylates

An arylative ring-opening reaction of cyclic allylmalonates with arylzinc reagents under nickel catalysis has been developed. Upon the ring-opening sp3C-sp3C bond cleavage, the allylic moiety serves as an allylic electrophile to reac