25109-28-8Relevant articles and documents
Organic compound and, electronic component using same, and electronic device
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Paragraph 0148-0152; 154, (2021/12/07)
The invention belongs to the field of organic materials, and relates to an organic compound and and an electronic device using the same, wherein the organic compound has the structure shown in Chemical Formula 1, the organic compound is applied to an organic electroluminescent device, and the performance of the device can be remarkably improved.
Ni-catalyzed Reductive Deaminative Arylation at sp3 Carbon Centers
Martin-Montero, Raul,Yatham, Veera Reddy,Yin, Hongfei,Davies, Jacob,Martin, Ruben
, p. 2947 - 2951 (2019/04/30)
A Ni-catalyzed reductive deaminative arylation at unactivated sp3 carbon centers is described. This operationally simple and user-friendly protocol exhibits excellent chemoselectivity profile and broad substrate scope, thus complementing existing metal-catalyzed cross-coupling reactions to forge sp3 C-C linkages. These virtues have been assessed in the context of late-stage functionalization, hence providing a strategic advantage to reliably generate structure diversity with amine-containing drugs.
Nickel-Catalyzed Cross-Coupling of Redox-Active Esters with Boronic Acids
Wang, Jie,Qin, Tian,Chen, Tie-Gen,Wimmer, Laurin,Edwards, Jacob T.,Cornella, Josep,Vokits, Benjamin,Shaw, Scott A.,Baran, Phil S.
, p. 9676 - 9679 (2016/08/10)
A transformation analogous in simplicity and functional group tolerance to the venerable Suzuki cross-coupling between alkyl-carboxylic acids and boronic acids is described. This Ni-catalyzed reaction relies upon the activation of alkyl carboxylic acids as their redox-active ester derivatives, specifically N-hydroxy-tetrachlorophthalimide (TCNHPI), and proceeds in a practical and scalable fashion. The inexpensive nature of the reaction components (NiCl2?6 H2O—$9.5 mol?1, Et3N) coupled to the virtually unlimited commercial catalog of available starting materials bodes well for its rapid adoption.