2565-83-5

Basic information

• Product Name: (Z)-1-methoxy-3,7-dimethylocta-2,6-diene
• Synonyms: (Z)-1-methoxy-3,7-dimethylocta-2,6-diene;6-Octadiene, 1-methoxy-3,7-dimethyl-, (Z)-2;Neryl methyl ether;(2Z)-1-Methoxy-3,7-dimethyl-2,6-octadiene;[(2Z)-3,7-Dimethyl-2,6-octadienyl]methyl ether;(2Z)-1-Methoxy-3,7-dimethylocta-2,6-diene
• CAS NO: 2565-83-5
• Molecular Formula: C₁₁H₂₀O
• Molecular Weight: 168.2759
• EINECS: 219-897-7
• Mol File: 2565-83-5.mol
• Article Data: 15

Chemical Properties

• Boiling Point: 220.3°Cat760mmHg
• Flash Point: 73.5°C
• Appearance: /
• Density: 0.827g/cm³
• Vapor Pressure: 0.169mmHg at 25°C
• Refractive Index: 1.449
• CAS DataBase Reference: (Z)-1-methoxy-3,7-dimethylocta-2,6-diene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-methoxy-3,7-dimethylocta-2,6-diene(2565-83-5)
• EPA Substance Registry System: (Z)-1-methoxy-3,7-dimethylocta-2,6-diene(2565-83-5)

Safety Data

• Hazardous Substances Data: 2565-83-5(Hazardous Substances Data)

Usage

General Description

(Z)-1-methoxy-3,7-dimethylocta-2,6-diene, also known as myrcene, is a natural organic compound found in the essential oils of various plants, including cannabis, hops, and bay. It is a volatile liquid with a fruity and earthy aroma, and is commonly used in the fragrance and flavor industries. Myrcene has been found to have sedative, analgesic, and anti-inflammatory properties, and is also known to enhance the effects of THC, the psychoactive compound in cannabis. Additionally, myrcene has been studied for its potential as an antitumor and antimutagenic agent. Overall, myrcene is a versatile and bioactive compound with various potential applications in medicine and industry.

InChI:InChI=1/C11H20O/c1-10(2)6-5-7-11(3)8-9-12-4/h6,8H,5,7,9H2,1-4H3/b11-8-

Upstream product

• 6138-90-5 geranyl bromide 
• 124-41-4 sodium methylate 
• 186581-53-3 diazomethane 
• 106-24-1 Geraniol 
• 74-88-4 methyl iodide 
• 67-56-1 methanol 
• 78-70-6 3,7-dimethylocta-1,6-dien-3-ol 
• 106-25-2 Nerol 
• 78055-70-6 trimethyl[(E)-3,7-dimethylocta-2,6-dienyl]silane 
• 1445-45-0 Trimethyl orthoacetate 
• 149-73-5 trimethyl orthoformate 
• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 
• 2565-83-5 geraniol methyl ether 
• 81678-26-4 2-nerylmercapto-1-methylimidazole 

Downstream Products

• 2565-77-7 α-Cyclogeraniol-methylether 
• 123-35-3 7-methyl-3-methene-1,6-octadiene 
• 53652-01-0 (Z)-N,N-Dimethyl-(3,7-dimethyl-2,6-octadienyl)amine 
• 51768-88-8 (E)-N,N-Dimethyl-(3,7-dimethyl-2,6-octadienyl)amine 
• 76027-12-8 (E)-N,N-Dimethyl-(2-ethylidene-6-methyl-5-heptenyl)amine 
• 2565-83-5 geraniol methyl ether 
• 141-27-5 3,7-dimethyl-2,6-octadienal 
• 464-72-2 tetraphenylethane-1,2-diol 
• 1352563-26-8 (E)-4-(5-methoxy-3-methylpent-3-en-1-yl)-3,3-dimethyl-2,2-diphenyloxetane 
• 4428-13-1 1,1,2-Triphenylethanol 
• 13955-48-1 (3RS,3aRS,7aSR)-3,6-dimethyl-2,3,3a,4,5,7a-hexahydrobenzofuran 
• 13955-48-1 (3S,3aR,7aS)-3,6-Dimethyl-2,3,3a,4,5,7a-hexahydro-benzofuran 
• 13341-72-5 (+/-)-3,6-dimethyl-5,6,7,7a-tetrahydrobenzofuran-2(4H)-one 
• 494-90-6 menthofuran 

Relevant articles and documents

Synergic actions of BEA-type zeolites and ultrasonic irradiation in conversion of geraniol

The geraniol conversion reaction was initiated by the simultaneous action of micro- and micro-mesoporous BEA-type zeolites and ultrasonic irradiation (UMR-300B hybrid reactor, 25 kHz, 100-900 W; SRF-1, 20-60 kHz, 100 W). Geraniol by ultrasonic irradiation at 27-100 °C, had a low degree of conversion, upto 2 %. Geraniol was a resistant to ultrasound in argon atmosphere solutions of N,Ndimethylformamide and methanol. In methanolic solution, geraniol was actively converted to linalool and to methyl ethers of linalool and nerol with the selectivity of 80 % on zeolite BEA-25 under ultrasonic irradiation in air at 30 °C. Using BEA-type zeolite/ultrasonicassisted reaction was increased the degree of conversion of geraniol, the selectivity and yield to linalool and nerol on the most active RBEA-25 zeolite by prolonged ultrasonic irradiation (1.5-5 h) or under combined ultrasound and microwave irradiation (US 300 W/MW 550 W, 1.5 h, 80 °C).

Bis(phosphine)cobalt dialkyl complexes for directed catalytic alkene hydrogenation

Planar, low-spin cobalt(II) dialkyl complexes bearing bidentate phosphine ligands, (P - P)Co-(CH2SiMe3)2, are active for the hydrogenation of geminal and 1,2-disubstituted alkenes. Hydrogenation of more hindered internal and endocyclic trisubstituted alkenes was achieved through hydroxyl group activation, an approach that also enables directed hydrogenations to yield contrasteric isomers of cyclic alkanes.

Allylic and allenic halide synthesis via NbCl5- and NbBr 5-mediated alkoxide rearrangements

(Chemical Equation Presented) Addition of NbCl5 or NbBr 5 to a series of magnesium, lithium, or potassium allylic or propargylic alkoxides directly provides allylic or allenic halides. Halogenation formally occurs through a metallahalo-[3,3] rearrangement, although concerted, ionic, and direct displacement mechanisms appear to operate competitively. Transposition of the olefin is equally effective for allylic alkoxides prepared by nucleophilic addition, deprotonation, or reduction. Experimentally, the niobium pentahalide halogenations are rapid, afford essentially pure (E)-allylic or -allenic halides after extraction, and are applicable to a range of aliphatic and aromatic alcohols, aldehydes, and ketones. 2009 American Chemical Society.