2669-89-8Relevant articles and documents
The vinyl radical investigated by infrared diode laser kinetic spectroscopy
Kanamori, Hideto,Endo, Yasuki,Hirota, Eizi
, p. 197 - 205 (1990)
A c-type band was observed at around 895 cm-1 by infrared diode laser kinetic spectroscopy combined with the excimer laser photolysis of vinyl halides at 193 nm and was assigned to the CH2 wagging mode of the vinyl radical.The band was found to consist of two component bands separated by 0.0541(11) cm-1.Both component bands showed clearly the statistical weight in an alternative way, that is, of one shows the weight 1:3 for even:odd Ka levels, the other exhibits 3:1, indicating that the radical is of C2υ effective symmetry, executing a double-minimum motion probably associated with the C-H in-plane rocking vibration.The upper states of the two bands were found to be perturbed weakly, possibly by a Coriolis interaction with the first overtone state of the C-H rocking mode.
193 nm photolysis of vinyl bromide: Nascent product distribution of the C2H3Br→C2H2 (vinylidene)+HBr channel
Liu,Letendre,Dai
, p. 1734 - 1741 (2007/10/03)
The internal energy content of fragment HBr and C2H2 following photolysis of the precursor, vinyl bromide, at 193 nm was determined using time-resolved Fourier transform spectroscopy (TR FTS). Data taken 1 μs after the laser photolys
Site-specific dissociation dynamics of ethylene at 157 nm: atomic and molecular hydrogen elimination
Lin, Jim J.,Wang, Chia C.,Lee, Yuan T.,Yang, Xueming
, p. 9668 - 9677 (2007/10/03)
Photodissociation of five ethylene isotopomers at 157 nm was studied using a molecular beam apparatus. From this study, complete and interesting information on the site and isotope effects on the molecular hydrogen elimination processes from ethylene were also detected. Using the new improved experimental technique, dynamical differences between different microchannels of molecular hydrogen elimination processes from ethylene were also detected. Site and isotopic effects on the molecular hydrogen elimination processes were also clearly observed.