27143-34-6Relevant articles and documents
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Bonnet,R. et al.
, p. 2439 - 2444 (1976)
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Dermer,Dysinger
, p. 750 (1939)
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Radical additions to olefins in the presence of iodobenzenediacetate: An easy route to alkyl dithiocyanates
De Mico, Antonella,Margarita, Roberto,Mariani, Andrea,Piancatelli, Giovanni
, p. 1889 - 1892 (2007/10/03)
We describe a new application of iodobenzenediacetate (IBDA), which is able to oxidize thiocyanate anion to the corresponding radical. Subsequent addition to nucleophilic olefins leads to dithiocyanate derivatives. The radical addition to olefins is more effective when performing the thiocyanation reaction in presence of Mg(ClO4)2 or TEMPO.
KINETICS AND DOPING EFFECT IN THE ADDITION OF 2,4-DINITROPHENYLSULFENYL CHLORIDE AND DITHIOCYANOGEN TO OLEFINS
Skorobogatova, E. V.,Grudzinskaya, E. Yu.,Afanas'ev, P. S,Kartashov, V. R.,Zefirov, N. S.,Caple, R.
, p. 1814 - 1822 (2007/10/02)
The rate of the doping addition in the reactions of 2,4-dinitrophenylsulfenyl chloride with cyclohexene an methylenecyclobutane and of dithiocyanogen with cyclohexene and substituted styrenes in the presence of lithium perchlorate is described by the normal salt effect equation.On the other hand, the rate of formation of the doping products may exceed or lag behind the increase in the total reaction rate.These results were interpreted in the framework of an ion-pair mechanism.