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2766-43-0

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2766-43-0 Usage

Chemical Properties

Liquid

Uses

Different sources of media describe the Uses of 2766-43-0 differently. You can refer to the following data:
1. Boc-L-serine methyl ester is a derivative of L-Serine Methyl Ester Hydrochloride (S271005) derivative. Boc-L-serine methyl ester is an amino acid derivative used in the preparation of Tn antigen, L-glutamic acid p-nitroanilide analogs and new biomedical polymers having Serine and Threonine side groups.
2. N-tert-Butoxycarbonyl-L-serine Methyl Ester is an amino acid derivative used in the preparation of Tn antigen, L-glutamic acid p-nitroanilide analogs and new biomedical polymers having Serine and Threonine side groups.

Check Digit Verification of cas no

The CAS Registry Mumber 2766-43-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,7,6 and 6 respectively; the second part has 2 digits, 4 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 2766-43:
(6*2)+(5*7)+(4*6)+(3*6)+(2*4)+(1*3)=100
100 % 10 = 0
So 2766-43-0 is a valid CAS Registry Number.
InChI:InChI=1/C9H17NO5/c1-9(2,3)15-8(13)10-6(5-11)7(12)14-4/h6,11H,5H2,1-4H3,(H,10,13)/t6-/m0/s1

2766-43-0 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • TCI America

  • (B2073)  N-(tert-Butoxycarbonyl)-L-serine Methyl Ester  >95.0%(HPLC)(N)

  • 2766-43-0

  • 5g

  • 735.00CNY

  • Detail
  • TCI America

  • (B2073)  N-(tert-Butoxycarbonyl)-L-serine Methyl Ester  >95.0%(HPLC)(N)

  • 2766-43-0

  • 25g

  • 2,230.00CNY

  • Detail
  • Alfa Aesar

  • (H59889)  N-Boc-L-serine methyl ester, 95%   

  • 2766-43-0

  • 2g

  • 226.0CNY

  • Detail
  • Alfa Aesar

  • (H59889)  N-Boc-L-serine methyl ester, 95%   

  • 2766-43-0

  • 10g

  • 1076.0CNY

  • Detail
  • Aldrich

  • (410489)  Boc-Ser-OMe  95%

  • 2766-43-0

  • 410489-1G

  • 288.99CNY

  • Detail
  • Aldrich

  • (410489)  Boc-Ser-OMe  95%

  • 2766-43-0

  • 410489-10G

  • 1,318.36CNY

  • Detail

2766-43-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name methyl (2S)-3-hydroxy-2-[(2-methylpropan-2-yl)oxycarbonylamino]propanoate

1.2 Other means of identification

Product number -
Other names methyl N-t-butoxycarbonyl-D,L-serinate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2766-43-0 SDS

2766-43-0Relevant articles and documents

Stereoselective synthesis of (-)-α-kainic acid and (+)-α-allokainic acid via trimethylstannyl-mediated radical carbocyclization and oxidative destannylation

Hanessian, Stephen,Ninkovic, Sacha

, p. 5418 - 5424 (1996)

(-)-α-Kainic acid (1) and its C4 epimer (+)-α-allokainic acid (2) have been prepared from L-serine. The requisite stereochemical array in (-)-α-kainic acid (1) was introduced using a trimethylstannyl radical carbocyclization of a diene, which gave the 2,3-trans/3,4-cis and 2,3-trans/3,4-trans componnds in a 2.8:1 ratio and in high yield. The destannylation of the trisubstituted pyrrolidine nucleus was achieved via an oxidative cleavage of the C-Sn bond with ceric ammonium nitrate. This provided a dimethyl acetal that was further transformed into the intended α-kainic acid. When the same radical carbocyclization was attempted on a triene, the 2,3-trans/3,4-trans and the 2,3-trans/3,4-cis adducts were obtained in a 2.5:1 ratio, respectively. This approach was used to synthesize (+)-α-allokainic acid.

Simple and efficient procedure for a multigram synthesis of both trans - And cis -1-Amino-2-(trifluoromethyl)cyclopropane-1-carboxylic Acid

Artamonov, Olexiy S.,Mykhailiuk, Pavel K.,Voievoda, Nataliia M.,Volochnyuk, Dmitry M.,Komarov, Igor V.

, p. 443 - 446 (2010)

A simple and efficient procedure for the multigram synthesis of both (±)-trans- and (±)-cis-1-amino-2-(trifluoromethyl)cyclopropane-1- carboxylic acid was developed. The key step of the synthesis is the addition of 1-diazo-2,2,2-trifluoroethane to methyl 2-[(tert-butoxycarbonyl)amino]acrylate, followed by thermal decomposition of the resulting pyrazoline. Gram quantities of trans- and cis-1-amino-2-(trifluoromethyl)cyclopropane-1-carboxylic acid were easily prepared from l-serine in one synthetic run. Georg Thieme Verlag Stuttgart - New York.

Efficient Hydro- and Organogelation by Minimalistic Diketopiperazines Containing a Highly Insoluble Aggregation-Induced, Blue-Shifted Emission Luminophore**

Molkenthin, Martin,Nachtsheim, Boris J.,Nau, Werner M.

supporting information, p. 16488 - 16497 (2021/10/25)

We report the synthesis, gelation abilities and aggregation-induced, blue-shifted emission (AIBSE) properties of two minimalistic diketopiperazine-based gelators. Despite containing a highly insoluble luminophore that makes up more than half of their respective molecular masses, efficient hydrogelation by multiple stimuli for one and efficient organogelation for the other compound are reported. Insights into the aggregation and gelation properties were gained through examination of the photophysical and material properties of selected gels, which are representative of the different modes of gelation. The synthesis of the gelators is highly modular and based on readily available amino acid building blocks, allowing the efficient and rapid diversification of these core structures and fine-tuning of gel properties.

Late-Stage Intermolecular Allylic C-H Amination

Clark, Joseph R.,Dixon, Charlie F.,Feng, Kaibo,Han, Wei,Ide, Takafumi,Koch, Vanessa,Teng, Dawei,Wendell, Chloe I.,White, M. Christina

supporting information, p. 14969 - 14975 (2021/10/01)

Allylic amination enables late-stage functionalization of natural products where allylic C-H bonds are abundant and introduction of nitrogen may alter biological profiles. Despite advances, intermolecular allylic amination remains a challenging problem due to reactivity and selectivity issues that often mandate excess substrate, furnish product mixtures, and render important classes of olefins (for example, functionalized cyclic) not viable substrates. Here we report that a sustainable manganese perchlorophthalocyanine catalyst, [MnIII(ClPc)], achieves selective, preparative intermolecular allylic C-H amination of 32 cyclic and linear compounds, including ones housing basic amines and competing sites for allylic, ethereal, and benzylic amination. Mechanistic studies support that the high selectivity of [MnIII(ClPc)] may be attributed to its electrophilic, bulky nature and stepwise amination mechanism. Late-stage amination is demonstrated on five distinct classes of natural products, generally with >20:1 site-, regio-, and diastereoselectivity.

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