27826-42-2

Basic information

• Product Name: 1-nitro-4-(propylsulfanyl)benzene
• CAS NO: 27826-42-2
• Molecular Formula: C₉H₁₁NO₂S
• Molecular Weight: 197.2541
• Mol File: 27826-42-2.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 315.8°C at 760 mmHg
• Flash Point: 144.8°C
• Density: 1.19g/cm³
• Vapor Pressure: 0.000794mmHg at 25°C
• Refractive Index: 1.575
• CAS DataBase Reference: 1-nitro-4-(propylsulfanyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-nitro-4-(propylsulfanyl)benzene(27826-42-2)
• EPA Substance Registry System: 1-nitro-4-(propylsulfanyl)benzene(27826-42-2)

Safety Data

• Hazardous Substances Data: 27826-42-2(Hazardous Substances Data)

Usage

Physical state

Pale yellow solid

Molecular weight

199.24 g/mol

Common uses

Organic synthesis, intermediate in production of pharmaceuticals, dyes, and agricultural chemicals, reagent in preparation of various organic compounds

Potential properties

Antibacterial, antifungal

Applications

Building block in materials science and nanotechnology

Handling precautions

Toxic and harmful if ingested or inhaled

Upstream product

• 107-03-9 1-thiopropane 
• 100-00-5 4-chlorobenzonitrile 
• 1849-36-1 para-nitrobenzenethiol 
• 100-32-3 di(p-nitrophenyl) disulfide 
• 106-94-5 propyl bromide 
• 21865-11-2 1-nitro-4-(propylsulfinyl)benzene 
• 350-46-9 4-Fluoronitrobenzene 
• 100-01-6 4-nitro-aniline 
• 629-19-6 Dipropyl disulfide 
• 636-98-6 p-nitrobenzene iodide 
• 71-23-8 propan-1-ol 
• 2137-92-0 4-nitrophenyl thiocyanate 
• 45797-13-5 4-nitrophenylthiolate 
• 107-08-4 1-iodo-propane 

Downstream Products

• 189639-05-2 2-[(2-hydroxy-ethyl)-(4-propylsulfanyl-phenyl)-amino]-ethanol 
• 189639-08-5 bis(2-chloroethyl)(4-propylthiophenyl)amine 
• 22133-40-0 4-aminophenyl propyl sulphide 

Relevant articles and documents

The Dependence of Ionic Liquid Solvent Effects on the Nucleophilic Heteroatom in SNAr Reactions. Highlighting the Potential for Control of Selectivity

Nucleophilic aromatic substitution (SNAr) reactions of 1-fluoro-4-nitrobenzene using similar nitrogen and sulfur nucleophiles were studied through extensive kinetic analysis in mixtures containing ionic liquids. The interactions of the ionic li

Ascorbic Acid Promoted Metal-Free Synthesis of Aryl Sulfides with Anilines Nitrosated in Situ by tert -Butyl Nitrite

A mild, metal-free synthesis of aryl sulfides has been disclosed. Aryl diazonium ion was generated by the in situ nitrosation of aniline, and it was reduced by ascorbic acid (vitamin C) to form aryl radical, which underwent a thiolation with disulfide to yield aryl sulfide. The reaction proceeded smoothly without heating or irradiation. This strategy was also expanded to the synthesis of aryl selenides.

Microwave efficient S-arylation of thiols with aryl iodides using supported metal nanoparticles

An efficient and green microwave-assisted heterogeneous S-arylation protocol, reported for the first time, provided excellent coupling conversions and selectivities in minutes of reaction using Fe (homocoupling) and Cu (cross-coupling) supported metal nanoparticles.