2829-31-4Relevant academic research and scientific papers
(17)O-ENRICHED α-AZOHYDROPEROXIDES: (17)O NMR SPECTROSCOPY, (17)O-LABELING REAGENTS
Baumstark, A. L.,Vasquez, P. C.,Balakrishnan, P.
, p. 2051 - 2054 (1985)
(17)O-enriched α-azohydroperoxides, prepared by autoxidation, are efficient (17)O-labeling reagents; (17)O NMR (CD3CN) of 2 showed broad signals at δ 254 and 204 PPM; the solvent dependence of the (17)O chemical shifts and the kinetics of ionic oxidations are interrelated.
A new peroxidase pathway for soybean lipoxygenase-1
Bombard, S.,Chopard-Casadevall, C.,Chottard, J. C.
, p. 417 - 427 (2007/10/02)
The phenylhydrazones (IH) of hexanal, benzaldehyde and 4'-benzyloxyacetophenone are mechanism-based inhibitors of the soybean lipoxygenase-1(L-1)-catalyzed dioxygenation of linoleic acid (KI = 0.2, 0.4, 5.6 μM respectively).These hydrazones are
GENERATION OF ARENEDIAZONIUM ION FROM MOLECULAR COMPLEX OF α-AZOHYDROPEROXIDE WITH SOLVENTS. A NEW ROUTE FOR DIAZONIUM ION
Tezuka, Takahiro,Ando, Setsuo
, p. 1621 - 1624 (2007/10/02)
Arenediazonium ions are generated from molecular complexes of α-azohydroperoxides with solvents (crystals or oils) under anhydrous conditions, when the solvated molecules are removed from these complexes.
Oxidation of Sulfides by Acyclic α-Azohydroperoxides
Baumstark, Alfons L.,Vasquez, Pedro C.
, p. 65 - 69 (2007/10/02)
The oxidation of sulfides with a series of substituted benzylazobenzene α-hydroperoxides (2a-f) produced the corresponding sulfoxides in good yield (ca. 90 percent) in C6D6 at 34 deg C.The reaction was found to be of the first order with respect to α-azohydroperoxide and to sulfide in aprotic medium.The reaction of BzSPh with acyclic α-azohydroperoxide 2a in C6D6 was found to be slower than the corresponding oxidation with 3-bromo -4,5-dihydro-5-hydroperoxy-4,4-dimethyl-3,5-diphenyl-3H-pyrazole in CDCl3.The relative reactivity series of sulfides with α-azohydroperoxide 2a was found to be Me2S (25)> BzSMe (14)> PhSMe (2.5)> BzSPh (1.0).This is similar to that observed for the reaction of the sulfides with hydrogen peroxide in protic solvent and reflects the relative nucleophilicities of the sulfides.The second-order rate constants for the reaction of a series of substituted benzylazobenzene α-hydroperoxides with PhSMe and BzSMe exhibited an excellent correlation with ? values.Both LFERs had ρ values of approximately 1.0.The results were interpreted to be consistent with nucleophilic attack of the sulfide on oxygen.Concomitant transfer of the hydroperoxy proton to the azo nitrogen would account for the lack of the requirement of general acid catalysis in aprotic medium.
