290835-85-7Relevant articles and documents
Method for preparing aldehyde or ketone by oxidizing reaction alcohol oxide
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Paragraph 0043-0046, (2021/11/03)
The invention relates to a method for preparing aldehyde or ketone by oxidizing reaction alcohol oxide. The invention belongs to the field of medicine and chemical engineering, and particularly relates to a nitric acid and organic nitrogen oxide composition as a catalyst. The invention is prepared by the oxidation reaction of alcohol, wherein the oxidant is oxygen, and the nitric acid and organic nitrogen oxide composition are used as a catalytic system. The reaction is homogeneous reaction, and the catalytic system is simplified. The method is simple and convenient to operate, high in yield and low in cost. The invention is a very economical and simple method for preparing aldehyde or ketone from alcohol, and is suitable for industrial production.
Zinc(II)-catalyzed oxidation of alcohols to carbonyl compounds with chloramine-T
Wang, Peng,Cai, Jin,Yang, Jiabin,Sun, Chunlong,Li, Lushen,Hu, Huayou,Ji, Min
supporting information, p. 533 - 535 (2013/02/25)
Efficient oxidation of primary and secondary alcohols to the corresponding carbonyl compounds can be carried out in acetonitrile, using chloramine-T in the presence of catalytic zinc(II) salts. Primary alcohols are selectively oxidized to aldehydes without carboxylic acid byproduct.