29800-45-1

Upstream product

• 67-56-1 methanol 
• 14114-06-8 cyclopropylidenecyclohexane 
• 524-38-9 N-hydroxyphthalimide 

Downstream Products

• 76785-92-7 1-cyclohexyl-3-iodo-1-propanone 
• 60211-19-0 spiro[3.5]nonan-1-ol 
• 56078-05-8 Methyl-1-(2',2'-dimethoxyethyl)-cyclohexan-1-carboxylat 
• 41487-76-7 methyl 1-(2-oxoethyl)cyclohexane-1-carboxylate 
• 41487-75-6 Methyl-1-(2',2'-dibrom-ethyl)-cyclohexan-1-carboxylat 
• 825-04-7 methyl 1-methylcyclohexanecarboxylate 
• 721965-22-6 1-[(Z)-3-phenyl-1-propenyl]spiro[4.5]decan-2-one 
• 811850-33-6 1-(3-benzoyloxy-1-propynyl)cyclobutanol-2-spirocyclohexane 

Relevant academic research and scientific papers

Strain-Promoted Oxidation of Methylenecyclopropane Derivatives using N-Hydroxyphthalimide and Molecular Oxygen in the Dark

The hydroperoxidation of alkylidenecyclopropanes and other strained alkenes using an N-hydroxylamine and molecular oxygen occurred in the absence of catalyst, initiator, or light. The oxidation reaction proceeds through a radical pathway that is initiated by autoxidation of the alkene substrate. The hydroperoxides were converted to their corresponding alcohols and ketones under mild conditions.

The chemistry of small-ring compounds. Part 47. Small-ring interference in the ozonolysis of cyclopropylidenecycloalkanes

Ozonolysis of olefins Ia-c containing a cyclpropylidene group, does not follow the classical Criegee mechanism but gives the anomalous products IIa-c, IIIa-c, IVa-c, and Va-c, as outlined in Scheme 2.None of these oxidation products contains the cycloprop

Polyspiranes, 5. Synthesis and Reactions of Functionalized Polyspiranes with Three- to Eight-Membered Central Ring - Polycyclopropylidenes (Rotanes)

The olefins 4, 5, and 6 have been proved to be valuable intermediates in the synthesis of functionalized polyspiranes and rotanes. Rotane (2, n = 3) and its methyl carboxylate 11 may be synthesized by way of 4, the functionalized polyspiranes 19, m = 1,2, 21, m = 0,1,2 and 1, m = 0,1,2, by way of 5.The ketones 1, m = 0,1,2 may then be transformed to the corresponding rotanes 2, n = 4,5,6.The factors controlling the pronounced regioselectivity in the cycloaddition of p-nitrobenzenesulfonyl azide to 19, m = 0,1,2, are discussed, the stepwise ring enlargement of 6 to yie ld 28 and 29 as potential precursors of 2, n = 7,8, is described.

Cyclopropylidenecyclanes Oxydation par l'acide peroxycarboximidique

The title reaction gives a mixture of four compounds .A 2-cyclohexyllideneoxetane is invoked as intermediary to account for the unusual lactone formation.