30565-44-7

Upstream product

• 4998-15-6 4-chlorophenylglyoxal 
• 67-63-0 isopropyl alcohol 
• 637-87-6 1-Chloro-4-iodobenzene 
• 201230-82-2 carbon monoxide 
• 30565-51-6 α-hydroxy-(4-chlorophenyl)acetic acid isopropyl ester 
• 103807-49-4 Bromo-(4-chloro-phenyl)-acetic acid isopropyl ester 
• 7099-88-9 4-chlorophenylglyoxylic acid 
• 34966-48-8 ethyl 2-(4-chlorophenyl)-2-oxoacetate 

Downstream Products

• 30565-51-6 α-hydroxy-(4-chlorophenyl)acetic acid isopropyl ester 
• 1596278-65-7 (S)-iso-propyl α-hydroxy-α-(4-chlorophenyl)acetate 

Relevant academic research and scientific papers

Enantio- and chemoselective Br?nsted-acid/Mg(nBu) 2 catalysed reduction of α-keto esters with catecholborane

The first enantio- and chemoselective Br?nsted-acid catalysed reduction of α-keto esters with catecholborane has been developed. The α-hydroxy esters were obtained under mild reaction conditions in virtually quantitative yields and excellent enantioselectivities. With slight modifications both enantiomers can be obtained without any loss of selectivity. This journal is the Partner Organisations 2014.

Utilization of natural sunlight and air in the aerobic oxidation of benzyl halides

Chemical equations presented. A novel, efficient oxidation of α-aryl halogen derivatives to the corresponding α-aryl carbonyl compounds at room temperature has been disclosed. Natural sunlight and air are successfully utilized in this approach through the combination of photocatalysis and organocatalysis. A plausible mechanism was proposed on the basis of the mechanistic studies.

Catalysis by Cobalt Schiff's Base Complexes in Highly Selective Conversion of Arylglyoxals to α-Aryl-α-hydroxyacetic Esters

Cobalt Schiff's base complexes catalyse highly selective conversion of arylglyoxals to α-aryl-α-hydroxyacetic esters in alcohols; Lewis acidity of CoIII species may be responsible to the catalysis.