3164-28-1

Basic information

• Product Name: Benzoxazole, 6-nitro-2-phenyl-
• CAS NO: 3164-28-1
• Molecular Formula: C13H8N2O3
• Molecular Weight: 240.218
• Mol File: 3164-28-1.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Benzoxazole, 6-nitro-2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoxazole, 6-nitro-2-phenyl-(3164-28-1)
• EPA Substance Registry System: Benzoxazole, 6-nitro-2-phenyl-(3164-28-1)

Safety Data

• Hazardous Substances Data: 3164-28-1(Hazardous Substances Data)

Upstream product

• 17200-30-5 6-nitrobenzo[d]oxazole 
• 98-88-4 benzoyl chloride 
• 100-52-7 benzaldehyde 
• 121-88-0 5-Nitro-2-aminophenol 
• 38880-89-6 N-(2-hydroxy-4-nitrophenyl)benzamide 
• 1663-61-2 triethoxymethylbenzene 
• 100-47-0 benzonitrile 
• 6192-52-5 p-toluenesulfonic acid monohydrate 
• 65-85-0 benzoic acid 
• 95-55-6 2-amino-phenol 
• 1624-53-9 2-(benzylideneamino)phenol 
• 5932-03-6 2-benzylideneamino-5-nitro-phenol 
• 3488-57-1 N-phenylbenzamidoxime 
• 833-50-1 2-phenylbenzo[d]oxazole 

Downstream Products

• 65-85-0 benzoic acid 
• 1198404-46-4 6-(3-pentyl-4H-1,2,4-triazol-4-yl)-2-phenylbenzo[d]oxazole 
• 1198404-45-3 6-(3-butyl-4H-1,2,4-triazol-4-yl)-2-phenylbenzo[d]oxazole 
• 1198404-43-1 2-phenyl-6-(3-propyl-4H-1,2,4-triazol-4-yl)benzo[d]oxazole 
• 1198404-41-9 6-(3-ethyl-4H-1,2,4-triazol-4-yl)-2-phenylbenzo[d]oxazole 
• 1198404-40-8 6-(3-methyl-4H-1,2,4-triazol-4-yl)-2-phenylbenzo[d]oxazole 
• 1134317-23-9 2-phenyl-6-(4H-1,2,4-triazol-4-yl)benzo[d]oxazole 
• 1198404-58-8 2-phenyl-6-(3-p-tolyl-4H-1,2,4-triazol-4-yl)benzo[d]oxazole 
• 1198404-57-7 6-(3-(4-methoxyphenyl)-4H-1,2,4-triazol-4-yl)-2-phenylbenzo[d]oxazole 
• 1198404-56-6 6-(3-(3-methoxyphenyl)-4H-1,2,4-triazol-4-yl)-2-phenylbenzo[d]oxazole 
• 1198404-55-5 6-(3-(4-chlorophenyl)-4H-1,2,4-triazol-4-yl)-2-phenylbenzo[d]oxazole 
• 53421-88-8 2-phenyl-1,3-benzoxazol-6-ylamine 

Relevant articles and documents

The unsuspected influence of the pyridyl-triazole ligand isomerism upon the electronic properties of tricarbonyl rhenium complexes: An experimental and theoretical insight

Two isomeric tricarbonyl rhenium(i) complexes, ReL1 and ReL2, that possess a 2-pyridyl-1,2,n-triazole (pyta) ligand (n = 4 and 3, respectively) connected to a 2-phenylbenzoxazole (PBO) moiety, were synthesized in good yields. The X-ray structures showed t

Electrochemical Generation of Hypervalent Bromine(III) Compounds

In sharp contrast to hypervalent iodine(III) compounds, the isoelectronic bromine(III) counterparts have been little studied to date. This knowledge gap is mainly attributed to the difficult-to-control reactivity of λ3-bromanes as well as to their challenging preparation from the highly toxic and corrosive BrF3 precursor. In this context, we present a straightforward and scalable approach to chelation-stabilized λ3-bromanes by anodic oxidation of parent aryl bromides possessing two coordinating hexafluoro-2-hydroxypropanyl substituents. A series of para-substituted λ3-bromanes with remarkably high redox potentials spanning a range from 1.86 V to 2.60 V vs. Ag/AgNO3 was synthesized by the electrochemical method. We demonstrate that the intrinsic reactivity of the bench-stable bromine(III) species can be unlocked by addition of a Lewis or a Br?nsted acid. The synthetic utility of the λ3-bromane activation is exemplified by oxidative C?C, C?N, and C?O bond forming reactions.

Method used for rapid preparation of benzo-heterocycle compound with physical grinding under solvent-free room temperature conditions

The invention discloses a method used for rapid preparation of benzo-heterocycle compound with physical grinding under solvent-free room temperature conditions. According to the method, glacial aceticacid is taken as a catalyst; at solvent-free room temperature conditions, physical grinding is adopted, reaction of 2-substituted arylamines (2-mercapto arylamine, 2-aminophenol, and o-phenylenediamine) and aromatic aldehydes is carried out using physical grinding. The method is friendly to the environment, is simple in operation, is safe, is low in cost, and is high in efficiency. Compared withthe prior art, the advantages are that: the method is suitable for a large amount of functional groups, yield is high, less by-product is generated, operation is simple, the method is safe, cost is low, and the method is friendly to the environment.