3170-96-5Relevant academic research and scientific papers
Interaction of aryloxychlorocarbenes with acetylenedicarboxylate: Novel formation of polyfunctional butadienes and 8-oxatricyclo[3.2.1.0 2.4]oct-6-enes
Cheng, Ying,Zhu, Qing,Li, Quan Song,Meth-Cohn, Otto
, p. 4840 - 4846 (2007/10/03)
The interaction of aryloxychlorocarbenes with dialkyl acetylenedicarboxylates has been examined. Thermolyses of 3-aryloxy-3- chlorodiazirines in the presence of acetylenedicarboxylate resulted in the formation of unexpected polyfunctional 1,3-butadienes and 8-oxatricyclo[3.2.1. 02.4]oct-6-enes or of 2-aryoxycarbonylmaleates dependent upon reaction conditions. This work confirmed the nucleophilicity of aryloxychlorocarbenes and underlined their synthetic potential.
Phenoxychlorocarbene, a Second Ambiphile
Moss, Robert A.,Perez, Leon A.,Wlostowska, Joanna,Guo, Wenjeng,Krogh-Jespersen, Karsten
, p. 4177 - 4180 (2007/10/02)
Phenoxychlorocarbene (PhOCCl) was generated by thermolysis (25 deg C) of 3-chloro-3-phenoxydiazirine and added to six alkenes, affording the corresponding cyclopropanes.The substrates and (relative) reactivities were tetramethylethylene (3.0), isobutene (
