82849-43-2Relevant academic research and scientific papers
Chlorofluorocarbene: First UV observation of a dihalocarbene in solution
Moss, Robert A.,Tian, Jingzhi,Sauers, Ronald R.,Skalit, Christopher,Krogh-Jespersen, Karsten
, p. 4053 - 4056 (2008/02/11)
Chlorofluorocarbene (CICF), generated by laser flash photolysis of chlorofluorodiazirine, absorbs at 368 nm in pentane. Absolute rate constants are reported for CICF additions to several alkenes and pyridine. CICF is less reactive toward alkenes than CCI
Unprecedented chemistry of an aryloxychlorodiazirine: Generation of a dihalodiazirine and diazirinone
Moss, Robert A.,Chu, Gaosheng,Sauers, Ronald R.
, p. 2408 - 2409 (2007/10/03)
The reaction of p-nitrophenoxychlorodiazirine with tetrabutylammonium fluoride follows three channels: (1) ～17% of p-nitrophenoxide/fluoride exchange to chlorofluorodiazirine and p-nitrophenol, (2) ～28% of Cl/F exchange to p-nitrophenoxyfluorodiazirine, and (3) ～55% of ipso fluoride attack, affording p-nitrofluorobenzene and the previously unknown diazirinone (diazacyclopropenone). Copyright
Phenoxychlorocarbene, a Second Ambiphile
Moss, Robert A.,Perez, Leon A.,Wlostowska, Joanna,Guo, Wenjeng,Krogh-Jespersen, Karsten
, p. 4177 - 4180 (2007/10/02)
Phenoxychlorocarbene (PhOCCl) was generated by thermolysis (25 deg C) of 3-chloro-3-phenoxydiazirine and added to six alkenes, affording the corresponding cyclopropanes.The substrates and (relative) reactivities were tetramethylethylene (3.0), isobutene (
