3183-57-1

Basic information

• Product Name: Ethanone, 1-(1-phenylcyclohexyl)-
• Synonyms: Acetyl-1-phenylcyclohexane;1-Phenylcyclohexylmethylketon;1-(1-phenyl-cyclohexyl)-ethanone;1-<1-Phenyl-cyclohexyl>-ethan-1-on;1-acetyl-1-phenylcyclohexane;1-(1-Phenyl-cyclohexyl)-aethanon
• CAS NO: 3183-57-1
• Molecular Formula: C14H18O
• Molecular Weight: 202.296
• Mol File: 3183-57-1.mol
• Article Data: 3

Chemical Properties

• Melting Point: 36 - 37.5 °C (methanol)
• CAS DataBase Reference: Ethanone, 1-(1-phenylcyclohexyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(1-phenylcyclohexyl)-(3183-57-1)
• EPA Substance Registry System: Ethanone, 1-(1-phenylcyclohexyl)-(3183-57-1)

Safety Data

• Hazardous Substances Data: 3183-57-1(Hazardous Substances Data)

Upstream product

• 2890-42-8 1-phenylcyclohexylcarbonyl chloride 
• 506-82-1 dimethylcadmium 
• 75-16-1 methylmagnesium bromide 
• 108-94-1 cyclohexanone 
• 103-79-7 1-phenyl-acetone 
• 1135-67-7 1-phenyl-cyclohexanecarboxylic acid 
• 712-50-5 Cyclohexyl phenyl ketone 
• 3674-77-9 2-methyl-2-phenyl-1,3-dioxolane 
• 7664-93-9 sulfuric acid 
• 1139-06-6 1-hydroxy-α-methyl-α-phenyl-cyclohexanemethanol 
• 56-23-5 tetrachloromethane 
• 7446-70-0 aluminium trichloride 
• 2892-99-1 (1-methylcyclohexyl)(phenyl)methanone 
• 36337-13-0 3-Phenyl-8-bromoctan-2-on 

Downstream Products

• 80606-02-6 1-Phenylcyclohexylmethylketoxim-pikrat 
• 1344924-39-5 1-(1-phenylcyclohexyl)ethan-1-ol 
• 1344956-92-8 1-(1-phenylcyclohexyl)ethan-1-ol 
• 1185018-48-7 3-dimethylamino-1-(1-phenyl-cyclohexyl)-propenone 
• 2890-38-2 1-Phenylcyclohexylmethylketoxim 

Relevant articles and documents

Enantioselective borohydride reduction of aliphatic ketones catalyzed by ketoiminatocobalt(iii) complex with 1-chlorovinyl axial ligand

For the enantioselective borohydride reduction of aliphatic ketones, the optically active ketoiminatocobalt(II) catalysts was successfully designed based on their axial ligand. Instead of chloroform for the aryl ketone reduction, various axial ligand precursors were examined for the aliphatic ketone. Consequently, 1, 1, 1-trichloroethane was found to be the most effective activator of the cobalt(II) complexes to generate the corresponding 1-chlorovinyl cobalt(III) derivatives as the reactive intermediate. Several aliphatic ketones were successfully reduced to afford the corresponding secondary alcohols with high enantioselectivities.

Wanderungstendenzen cyclischer, polycyclischer und methylverzweigter Alkylreste bei der Beckmann-Umlagerung

The migration aptitudes of polycyclic bridgehead groups, cycloalkyl groups as well as of β-, γ- and δ-branched alkyl groups in the Chapman variant of the Beckmann rearrangement were determined.From these data it is concluded that at transition state 2 the migrating group is not resembling a planarised carbenium ion R+, but rather a pentacoordinated carbonium ion structure.Because only small geometrical changes occur in the migrating group vertical stabilisation of charge at transition state is believed to have significant influence on the migration aptitudes.