3190-01-0

Basic information

• Product Name: meso-α.α'-bis-benzylidenamino-bibenzyl
• Synonyms: meso-α.α'-bis-benzylidenamino-bibenzyl
• CAS NO: 3190-01-0
• Molecular Weight: 388.512
• Mol File: 3190-01-0.mol

Chemical Properties

• CAS DataBase Reference: meso-α.α'-bis-benzylidenamino-bibenzyl(CAS DataBase Reference)
• NIST Chemistry Reference: meso-α.α'-bis-benzylidenamino-bibenzyl(3190-01-0)
• EPA Substance Registry System: meso-α.α'-bis-benzylidenamino-bibenzyl(3190-01-0)

Safety Data

• Hazardous Substances Data: 3190-01-0(Hazardous Substances Data)

Upstream product

• 780-25-6 N-benzylidene benzylamine 
• 951-87-1 rac-1,2-diphenylethylene-1,2-diamine 
• 100-52-7 benzaldehyde 
• 90-02-8 salicylaldehyde 
• 41013-29-0 N,N'-disalicylidene-(R,S)(S,R)-1,2-diphenyl-1,2-ethanediamine 
• 58519-80-5 meso-1,2-bis(2-hydroxyphenyl)-1,2-ethylenediamine 
• 951-87-1 meso-1,2-diphenyl-1,2-diaminoethane 
• 64-17-5 ethanol 
• 92-29-5 hydrobenzamide 
• 573-33-1 (4R,5S)-2,4,5-Triphenyl-4,5-dihydro-1H-imidazole 
• 104-71-2 N,N'-bis(benzyliden)ethylendiamine 
• 1159-87-1 N,N'-Bis--meso-1,2-diamino-1,2-diphenyl-ethan 

Downstream Products

• 3190-01-0 racem-N,N'-dibenzylidene-bibenzyl-α,α'-diyldiamine 
• 3190-01-0 N,N'-dibenzylidene-1,2-diphenylethane-1,2-diamine 
• 24431-19-4 N¹,N²-dibenzyl-1,2-diphenylethane-1,2-diamine 
• 27549-76-4 meso-N,N'-dibenzyl-1,2-diphenyl-1,2-diaminoethane 
• 90155-46-7 1R,2R-trans-diphenyl-1,2-ethanediamine 
• 100-52-7 benzaldehyde 
• 951-87-1 rac-1,2-diphenylethylene-1,2-diamine 

Relevant articles and documents

Synthesis of cis bis-β-lactams via Staudinger cycloaddition reaction using C2-symmetric 1,2-diamines

An efficient stereoselective synthesis of bis-β-lactams via cycloaddition reaction (Staudinger reaction) of ketenes with bisimines derived from C2-symmetric 1, 2-diamines is described. The reaction provided diastereomeric mixture of meso and C2-symmetric cis-bis-β- lactams with higher selectivity for meso-bis-β-lactams.

Discovery of chiral catalysts by asymmetric activation for highly enantioselective diethylzinc addition to imines: Using racemic and achiral diimines as effective activators

A library of chiral zinc complexes formed in situ by the combination of achiral and racemic diimines with 3,3′-di(3,5-ditrifluoromethylphenyl)- BINOL and diethylzinc were evaluated in the asymmetric addition of diethylzinc to N-acylimines. In the presence of 10 mol % of chiral ligand 4 and racemic diimine 5, high enantioselectivities of up to 97% ee and yields of up to 96% were achieved for a wide range of aromatic imines in dichloromethane at -30°C.