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32195-55-4

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32195-55-4 Usage

Uses

Tetraphenylporphyrin manganese (III) chloride complex generally finds application in determining histidine in aqueous solutions by resonance light scattering technique.

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Check Digit Verification of cas no

The CAS Registry Mumber 32195-55-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,1,9 and 5 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 32195-55:
(7*3)+(6*2)+(5*1)+(4*9)+(3*5)+(2*5)+(1*5)=104
104 % 10 = 4
So 32195-55-4 is a valid CAS Registry Number.
InChI:InChI=1/C44H30N4.ClH.Mn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28,45,48H;1H;/q;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;

32195-55-4 Well-known Company Product Price

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  • Aldrich

  • (254754)  5,10,15,20-Tetraphenyl-21H,23H-porphinemanganese(III)chloride  95%

  • 32195-55-4

  • 254754-500MG

  • 1,054.17CNY

  • Detail
  • Sigma-Aldrich

  • (24897)  ChlorideionophoreI  Selectophore

  • 32195-55-4

  • 24897-50MG

  • 1,297.53CNY

  • Detail

32195-55-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name manganese(3+),10,12,13,23-tetraphenyl-21H-porphyrin,trichloride

1.2 Other means of identification

Product number -
Other names Magnesium meso-Tetraphenylporphine n-hydrate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:32195-55-4 SDS

32195-55-4Relevant articles and documents

Magnetocaloric effect and heat capacity of high-spin manganese complexes in a disperse state

Korolev,Aref'Ev,Lomova,Klyueva,Zakharov,Korolev

, p. 1631 - 1635 (2010)

Magnetothermal properties of high-spin chloro(2,3,7,8,12,13,17,18- octaethylporphyrinato)manganese(III), chloro(5,10,15,20-tetraphenylporphyrinato) manganese(III), bromo(5,10,15,20-tetraphenylporphyrinato)manganese(III), and (acetato)(5,10,15,20-tetraphenylporphyrinato)manganese(III) complexes as 6% water suspensions were determined by the microcalorimetric method at 298 K in a magnetic field of 0-1.0 T. It was established that when the magnetic field was applied, the temperature of the systems increases, leading to positive values of the magnetocaloric effect: the higher the magnetic field induction, the higher the values. It is shown that the dependences of the heat capacity of the complexes' solid particles on the magnetic field induction are of an extreme nature with a heat capacity in the area above 0.6 T less than that in the zero field. The regularities of the dynamics of the numerical values of the change in enthalpy and magnetic entropy of the manganese complexes when a growing magnetic field was applied and the regularities of the influence of the acidoligand in pentacoordinated complexes on their magnetothermal properties were considered.

Hydrogen-bonded chain structure of a six-coordinate 5,10,15,20-tetraphenylporphinatomanganese(III) complex

Hill, Jonathan P.,Santiago, Julio,Sugino, Takushi,Shiro, Motoo,Shimizu, Yo

, p. 107 - 111 (2001)

In methanolic solutions, disproportionation of the TCNQ anion radical to neutral TCNQ0 and the dianion TCNQ2- followed by aerobic oxidation of TCNQ2- results in the formation of methyl-4-dicyanomethylene benzoate anion (MDCB-). This anion coordinates to the manganese(III) atom of 5,10,15,20-tetraphenylporphinatomanganese(III) leading to the complex whose X-ray crystal structure is reported. The crystal had the monoclinic space group P21/n with unit cell dimensions a = 13.327(3), b = 20.236(6), c = 16.914(5) ? and β = 92.26(2)°. An important driving force behind the crystal packing is a hydrogen bonding interaction between non-identical ligands of adjacent molecules.

Cycloaddition reaction of propylene oxide and carbon dioxide over NaX zeolite supported metalloporphyrin catalysts

Zhang, Fengyong,Xie, Yujia,Liu, Pingle,Hao, Fang,Yao, Zhengjie,Luo, He'An

, p. 1894 - 1899 (2014)

Metalloporphyrin catalysts has attracted extensive attention as the result of their outstanding biomimetic catalytic properties. In this paper, different kinds of unsupported (Co(TPP), MnIII(TPP)Cl and CoIII(TPP)Cl) and NaX zeolite supported metalloporphy

Linkage Isomers of 4-Methylimidazolate Mn(II) Porphyrinates: Hindered or Unhindered?

Zhao, Jianping,Qian, Fei,Guo, Wenping,Li, Jianfeng,Lin, Zeyuan

, p. 7465 - 7474 (2021/05/26)

Three different manganese(II) porphyrins have been exploited to react with 4-methylimidazolate (4-MeIm-), and the five-coordinate products are characterized by ultraviolet-visible, single-crystal X-ray, and electronic paramagnetic resonance spectroscopies. Interestingly, 4-MeIm- is found to bond to the metal center through either of the two N atoms (N1 or N3), which yielded two linkage isomers with either an unhindered or a hindered ligand conformation, respectively. Investigations revealed it is the large metal out-of-plane displacements (Δ24 and Δ4 ≥ 0.59 ?) that have rendered the equivalence of two isomers with a small energy difference (5.2-8.3 kJ/mol). The nonbonded intra- and intermolecular interactions thus become crucial factors in the balance of linkage isomerization. All of the products in both solution and solid states show the same characteristic resonances of high-spin Mn(II) (S = 5/2) with g⊥ ≈ 5.9 and g⊥ ≈ 2.0 at 4 K, consistent with the weak effects of the axial ligand on core conformation and metal electronic configurations. Zero-field splitting parameters obtained through simulations are also reported.

Surface molecular engineering of axial-exchanged Fe(III)Cl- and Mn(III)Cl-porphyrins towards enhanced electrocatalytic ORRs and OERs

Attatsi, Isaac Kwaku,Zhu, Weihua,Liang, Xu

supporting information, (2020/03/23)

Herein, pyrene-pyridine (Pyr-Py) molecule was applied as the axial exchanged ligand to bridge Fe(III) and Mn(III)porphyrin immobilized on rGO. These axially exchanged metalloporphyrin functionalized nanocomposites revealed enhanced electrochemically catal

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