3254-32-8

Basic information

• Product Name: 6-O-benzoyl-1,2-O-(1-methylethylidene)hexofuranose
• CAS NO: 3254-32-8
• Molecular Formula: C₁₆H₂₀O₇
• Molecular Weight: 324.3258
• Mol File: 3254-32-8.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 502.1°C at 760 mmHg
• Flash Point: 184.2°C
• Density: 1.313g/cm³
• Vapor Pressure: 6.67E-11mmHg at 25°C
• Refractive Index: 1.552
• CAS DataBase Reference: 6-O-benzoyl-1,2-O-(1-methylethylidene)hexofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 6-O-benzoyl-1,2-O-(1-methylethylidene)hexofuranose(3254-32-8)
• EPA Substance Registry System: 6-O-benzoyl-1,2-O-(1-methylethylidene)hexofuranose(3254-32-8)

Safety Data

• Hazardous Substances Data: 3254-32-8(Hazardous Substances Data)

Upstream product

• 623-11-0 1-methyl-4-nitrosobenzene 
• 37614-73-6 1,2-O-isopropylidene-α-D-glucofuranose 3-O-benzoate 
• 13964-22-2 3-O-benzoyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 65-85-0 benzoic acid 
• 15354-69-5 5,6-anhydro-1,2-O-isopropylidene-α-D-glucofuranose 
• 98-88-4 benzoyl chloride 
• 18549-40-1 1,2-O-isopropylidene-α-D-glucofuranose 
• 81712-63-2 Benzoic acid (R)-2-benzhydryloxy-2-((3aR,5R,6S,6aR)-6-benzhydryloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethyl ester 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 14927-09-4 O¹,O²-isopropylidene-O³,O⁵-phenylboranediyl-α-D-glucofuranose 
• 23397-77-5 endo/exo-5,6-O-Benzylidene-1,2-O-isopropylidene-α-D-glucofuranose 

Downstream Products

• 78841-65-3 6-O-benzoyl-1,2-O-isopropylidene-3,5-di-O-(methylsulfonyl)-α-D-glucofuranose 
• 81712-63-2 Benzoic acid (R)-2-benzhydryloxy-2-((3aR,5R,6S,6aR)-6-benzhydryloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethyl ester 
• 983-79-9 benzophenone azine 
• 90-75-5 6-O-benzoyl-D-glucopyranose 
• 1003600-48-3 2,3-dideoxy-D-arabino-hept-2-enoic acid δ-lactone 4,6-diacetate 7-benzoate 
• 124572-55-0 (1R)-O²-acetyl-O³,O⁶-dibenzoyl-1-(6-benzoylamino-purin-9-yl)-D-xylo-1,4-anhydro-5-deoxy-hexitol 
• 51785-67-2 3,6-di-O-benzoyl-1,2-O-isopropylidene-5-deoxy-α-D-xylo-hexofuranose 
• 7057-09-2 1,2-O-isopropylidene-5-deoxy-α-D-glucofuranose 
• 78841-73-3 methyl 3-O-benzoyl-5-O-benzyl-6-deoxy-β-L-idofuranoside 
• 78841-72-2 methyl 3-O-benzoyl-5-O-benzyl-6-deoxy-α-L-idofuranoside 
• 78841-70-0 5-O-benzyl-6-deoxy-1,2-O-isopropylidene-β-L-idofuranose 
• 78841-76-6 methyl 5-O-benzyl-2,6-dideoxy-α-L-lyxo-hexofuranoside 
• 78841-75-5 methyl 2,3-anhydro-5-O-benzyl-α-L-gulofuranoside 
• 78841-74-4 methyl 3-O-benzoyl-5-O-benzyl-6-deoxy-2-O-p-tolylsulfonyl-α-L-idofuranoside 

Relevant articles and documents

Boronic esters as protective groups in carbohydrate chemistry: processes for acylation, silylation and alkylation of glycoside-derived boronates

Procedures for selective installation of acyl, silyl ether and para-methoxybenzyl (PMB) ether groups to glycoside substrates have been developed, employing phenylboronic esters as protected intermediates. The sequence of boronic ester formation, functiona

A concise total synthesis of cleistenolide

A concise total synthesis of cleistenolide has been achieved from D-glucose. The synthesis of cleistenolide proceeds in six steps from D-glucose diacetonide in 42.5% overall yield. Selective benzoylation and Still-Gennari olefination are the key reactions involved in the synthesis.

Control of regioselectivity in reactions of dialkylstannylene acetals. Part I. A dramatic reversal of regioselectivity in mono-p-toluenesulfonation reactions

The regioselectivities of p-toluenesulfonation reactions of dialkylstannylene acetals obtained from a number of carbohydrate-derived terminal 1,2-diols in the absence of added nucleophiles have been explored as functions of the carbohydrate structure, the