33046-45-6

Basic information

• Product Name: Ethanone, 2-[(4-methylphenyl)thio]-1-phenyl-
• CAS NO: 33046-45-6
• Molecular Formula: C15H14OS
• Molecular Weight: 242.342
• Mol File: 33046-45-6.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-[(4-methylphenyl)thio]-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-[(4-methylphenyl)thio]-1-phenyl-(33046-45-6)
• EPA Substance Registry System: Ethanone, 2-[(4-methylphenyl)thio]-1-phenyl-(33046-45-6)

Safety Data

• Hazardous Substances Data: 33046-45-6(Hazardous Substances Data)

Upstream product

• 10486-08-5 sodium p-thiocresolate 
• 532-27-4 1-chloroacetophenone 
• 106-45-6 para-thiocresol 
• 5285-74-5 4-tolyl thiocyanate 
• 5633-34-1 (benzoylmethylene)dimethylsulfurane 
• 51718-28-6 2,2-bis(p-tolylthio)acetophenone 
• 17530-89-1 p-tolyl phenacyl sulphoxide 
• 93-89-0 benzoic acid ethyl ester 
• 70-11-1 α-bromoacetophenone 
• 536-74-3 phenylacetylene 
• 16717-64-9 1-azidostyrene 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 98-86-2 acetophenone 
• 1021-45-0 phosphoric acid diethyl ester-(1-phenyl-vinyl ester) 

Downstream Products

• 18523-73-4 2,2-diphenylethenyl p-tolyl sulfide 
• 55164-43-7 5-methyl-2-phenylbenzothiophene 
• 108012-20-0 5-methyl-3-phenylbenzo[b]thiophene 
• 103-19-5 di(p-tolyl) disulfide 
• 57694-83-4 1,4,4-triphenyl-but-3-en-1-one 
• 51351-89-4 nitromethyl p-tolyl sulfone 
• 93-89-0 benzoic acid ethyl ester 
• 1586031-05-1 C₁₇H₁₈O₂S 
• 1248588-12-6 3-ethoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylprop-2-en-1-one 
• 108011-95-6 5-methyl-3-phenyl-benzo[b]thiophene-1,1-dioxide 
• 92697-23-9 5-methyl-2-phenylbenzo[b]thiophene-1,1-dioxide 
• 141362-05-2 (2,2-diphenyl-vinyl)-p-tolyl sulfoxide 
• 70312-74-2 1-(2,2-diphenyl-ethenesulfonyl)-4-methyl-benzene 
• 122772-72-9 (E)-3-(2-Chloro-phenyl)-1-phenyl-2-(toluene-4-sulfonyl)-propenone 

Relevant articles and documents

Electrocatalytic Synthesis of gem -Bisarylthio Enamines and α-Phenylthio Ketones via a Radical Process under Mild Conditions

The novel method for the synthesis of gem -bisarylthio enamines and α-phenylthio ketones was developed via the coupling of α-substituted vinyl azides with thiols in the presence of tetrabutylammonium iodide (TBAI) as a redox catalyst and electrolyte at ro

Practical and regioselective halo-trifluoromethylthiolation of sulfur ylides

A H2O mediated practical and highly regioselective chloro- and bromo-trifluoromethylthiolation of sulfur ylides is reported using a difunctionalization strategy. In the reaction sequence, sulfur ylides presumably react with an electrophilic trifluoromethylthiolating reagent to generate an α-SCF3 substituted sulfonium salt intermediate, which then undergoes a substitution with nucleophilic halogens. This journal is

Odorless, Regioselective Synthesis of Diaryl Sulfides and α-Thioaryl Carbonyls from Sodium Arylsulfinates via a Metal- Free Radical Strategy in Water

Regioselective arylthiolations of aromatic amines, arenols and ketones via C–H bond functionalization have been achieved with I2and PPh3in an aqueous system, whereby arylsulfenyl radicals are in situ generated from odorless sodium arylsulfinates. The arylsulfenyl radicals can react with free anilines containing electron-withdrawing groups and complex substrates (estrone and progesterone). Further experiments and quantum chemical calculations were also performed to deduce a mechanism for the formation of arylsulfenyl radicals. (Figure presented.).