33227-76-8

Basic information

• Product Name: 4-Aminophenyl(4-methylphenyl)amine
• Synonyms: 4-Aminophenyl(4-methylphenyl)amine;N1-(p-Tolyl)benzene-1,4-diamine
• CAS NO: 33227-76-8
• Molecular Formula: C₁₃H₁₄N₂
• Molecular Weight: 198.26
• Mol File: 33227-76-8.mol
• Article Data: 11

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-Aminophenyl(4-methylphenyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Aminophenyl(4-methylphenyl)amine(33227-76-8)
• EPA Substance Registry System: 4-Aminophenyl(4-methylphenyl)amine(33227-76-8)

Safety Data

• Hazardous Substances Data: 33227-76-8(Hazardous Substances Data)

Upstream product

• 620-89-3 4-methyl-N-(4-nitrophenyl)aniline 
• 623-11-0 1-methyl-4-nitrosobenzene 
• 586-96-9 Nitrosobenzene 
• 26053-94-1 acetic acid-(4-p-tolylazo-phenyl ester) 
• 7647-01-0 hydrogenchloride 
• 7664-93-9 sulfuric acid 
• 41018-61-5 N-phenyl-N-(p-tolyl)nitrous amide 
• 106-38-7 para-bromotoluene 
• 106-50-3 1,4-phenylenediamine 
• 106-49-0 p-toluidine 
• 106-40-1 4-bromo-aniline 
• 106-47-8 4-chloro-aniline 
• 100-00-5 4-chlorobenzonitrile 
• 123-31-9 hydroquinone 

Downstream Products

• 100723-80-6 [1,4]benzoquinone-imine-p-tolylimine 
• 63512-60-7 toluene-4-sulfonic acid-(4-p-toluidino-anilide) 
• 29813-87-4 N-(4-hydroxyphenyl)-p-toluidine 
• 18440-54-5 N-(4-Methylphenyl)-1,4-benzoquinone monoimine 
• 27174-04-5 4-Methyl-4'-isothiocyano-diphenylamin 

Relevant articles and documents

Antioxidant and method for preparing antioxidant

The invention discloses an antioxidant and a method for preparing the antioxidant. An intermediate 2 reacts with an intermediate 5 to obtain an intermediate 14, the intermediate 14 isoxidized with potassium permanganate, an esterification reaction is then carried out with an intermediate 13 to obtain an intermediate 15, the intermediate 15 is reduced with tin powder to obtain an intermediate 16, the intermediate 16 and the intermediate 8 are subjected to dehydration condensation, the antioxidant is prepared, the antioxidant contains a large number of sulfur atoms, the sulfur atoms can be oxidized to form sulfoxide and sulfone compounds, the antioxidant has good oxidation resistance, free radicals generated by macromolecules can be captured, then the free radical branching reaction is inhibited, and the antioxidant activity is improved. The oxidation resistance of the high-molecular material is improved, and the self relative molecular mass is large and is not easy to separate out from the high-molecular material.

Substituted anilino-benzothiazole-2-thioketone compound as well as preparation method and application thereof

The invention discloses a substituted anilino-benzothiazole-2-thioketone compound and a preparation method thereof. In addition, the invention also relates to an application of the compound in rubberproducts. The substituted anilino-benzothiazole-2-thioketone compound disclosed by the invention not only can promote rubber vulcanization, but also can prolong the service life of the rubber products.

CoII immobilized on an aminated magnetic metal-organic framework catalyzed C-N and C-S bond forming reactions: A journey for the mild and efficient synthesis of arylamines and arylsulfides

In this work, we report a simple and versatile method for the modification of a metal-organic framework (NH2-MIL53(Al)) in a step-wise manner. To characterize the synthesized nanostructured catalyst, a variety of spectroscopic and microscopic techniques including FT-IR, XRD, BET, TEM, FE-SEM, EDX, EDX-mapping, TGA, XPS, VSM, ICP-OES and CHN have been employed. Fe3O4@AMCA-MIL53(Al)-NH2-CoII NPs, which benefit from small nanocrystalline size (10-30 nm, according to the XRD and TEM data) in combination with the coexistence of magnetic nanoparticles, a metal-organic framework, and cobalt species, were found to be an excellent environment catalyst to promote the C-N and C-S cross coupling reactions. A wide range of functional substrates including electron-withdrawing and electron-donating aryl halides underwent the coupling reaction with aromatic/heteroaromatic/benzylic and aliphatic amines and sulfides. The results demonstrated that the yields of the target products were good to excellent and the catalyst can be recycled for at least seven recycling runs without a discernible decrease in its catalytic activity. Furthermore, the heterogeneity studies (such as hot filtration and poisoning tests) efficiently confirmed that the as-synthesized nanostructured catalyst is heterogeneous and completely stable under the reaction conditions. We hope that our study inspires more interest in designing novel catalysts based on using low-cost metal ions (such as cobalt) in the field of cross coupling reactions.