33929-52-1Relevant academic research and scientific papers
A palladium-catalyzed domino coupling process leading to anneiated pentafulvenes
Dyker, Gerald,Nerenz,Siemsen,Bubenitschek,Jones, Peter G.
, p. 1265 - 1269 (1996)
Annelated pentafulvenes 2, 10, 13, and 14 are efficiently accessible by a palladium-catalyzed domino coupling process of aryl substituted vinylic bromides 1, 9, 11, and 12. 5-Membered palladacycles 3 are discussed as key intermediates. VCH Verlagsgeselisc
Synthesis of 9-alkylidene-9H-fluorenes by a novel, palladium-catalyzed cascade reaction of aryl halides and 1-aryl-1-alkynes
Larock,Tian
, p. 7372 - 7379 (2007/10/03)
In the presence of a palladium catalyst and NaOAc, aryl iodides react with 1-aryl-1-alkynes to afford 9-alkylidene-9H-fluorenes in good yields. The products from this reaction are highly dependent on the base employed. This process appears to involve (1)
