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(2-bromo-1-phenyl-ethenyl)benzene, also known as 1-phenyl-2-bromoethenylbenzene, is an organic chemical compound characterized by the molecular formula C14H11Br. It is a colorless to pale yellow liquid that exhibits solubility in organic solvents but not in water. (2-bromo-1-phenyl-ethenyl)benzene is recognized for its utility as a building block in the synthesis of various organic compounds, particularly in the pharmaceutical and agrochemical industries.

13249-58-6

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13249-58-6 Usage

Uses

Used in Pharmaceutical and Agrochemical Industries:
(2-bromo-1-phenyl-ethenyl)benzene is utilized as a key building block in the synthesis of pharmaceuticals and agrochemicals, contributing to the development of new drugs and pesticides. Its unique structure allows for the creation of a wide range of chemical entities with potential therapeutic and pesticidal properties.
Used in Laboratory Research:
In laboratory settings, (2-bromo-1-phenyl-ethenyl)benzene serves as a reagent for various organic reactions, facilitating the synthesis of complex organic molecules. Its reactivity makes it a valuable tool for researchers in organic chemistry.
Used in Dye and Pigment Manufacturing:
(2-bromo-1-phenyl-ethenyl)benzene has potential applications in the manufacturing of dyes and pigments, where its chemical properties can be harnessed to produce a variety of colorants for different industries.
Used in Specialty Polymer Production:
(2-bromo-1-phenyl-ethenyl)benzene is also used in the production of specialty polymers, where its unique structure can impart specific properties to the resulting polymers, such as improved stability or reactivity.
Safety Precautions:
Due to the reactivity and potential hazards associated with (2-bromo-1-phenyl-ethenyl)benzene, it is crucial to follow proper safety precautions when handling and storing (2-bromo-1-phenyl-ethenyl)benzene. This includes using appropriate personal protective equipment, working in well-ventilated areas, and adhering to established safety protocols to minimize risks.

Check Digit Verification of cas no

The CAS Registry Mumber 13249-58-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,2,4 and 9 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 13249-58:
(7*1)+(6*3)+(5*2)+(4*4)+(3*9)+(2*5)+(1*8)=96
96 % 10 = 6
So 13249-58-6 is a valid CAS Registry Number.

13249-58-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name (2-bromo-1-phenylethenyl)benzene

1.2 Other means of identification

Product number -
Other names 2-bromo-1,1-diphenylethylene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13249-58-6 SDS

13249-58-6Relevant academic research and scientific papers

Synthesis and evaluation of thiophene-based organic dyes containing a rigid and nonplanar donor with secondary electron donors for use in dye-sensitized solar cells

Fuse, Shinichiro,Takahashi, Ryota,Maitani, Masato M.,Wada, Yuji,Kaiho, Tatsuo,Tanaka, Hiroshi,Takahashi, Takashi

, p. 508 - 517 (2016)

We demonstrate herein the divergent synthesis of six dyes containing our originally developed rigid and nonplanar donor with three different secondary electron donors (SEDs), namely thiophene, 4-methoxybenzene, and diphenylethene. Evaluation of the photop

A phenyl-removal strategy for accessing an efficient dual-state emitter in the red/NIR region guided by TDDFT calculations

Jiang, Lixia,Liang, Kangli,Shao, Qingqing,Wang, Hongming,Wang, Yigang,Xia, Guomin

, p. 13621 - 13626 (2020)

The development of molecules with efficient dual-state emission in the red/NIR region is significant for their broader application prospects in the biological field, but still remains a great challenge. Guided by in-depth TDDFT calculations, herein we fir

A kinetic, product and kinetic isotope effect investigation of the bromination of 1,1-diphenylethyIenes and of their 2,2-dideuterio derivatives

Bellucci, Giuseppe,Chiappe, Cinzia

, p. 581 - 584 (1997)

The kinetics of bromination of 1,1-diphenylethylene (1a), 4-trifluoromethyl-1,1-diphenylethylene (1b), and 1-(3-trifluoromethylphenyl)-1-(4-trifluoromethylphenyl)ethylene (1c) and of their 2,2-dideuterio derivatives have been investigated in 1,2-dichloroe

Visible-light-mediated radical addition/cyclization tandem reaction for the synthesis of 3-bromomethyl-3,4-dihydroisocoumarins

Li, Xing-Meng,Qian, Zhu-Ming,He, Yan-Hong,Guan, Zhi

, (2021)

A visible-light-mediated radical addition/cyclization tandem reaction for the synthesis of 3-bromomethyl-3,4-dihydroisocoumarins from 2-allylbenzaldehydes and diethyl 2,2-dibromomalonate is described. In this reaction, the bromine radical is generated fro

Light-Promoted Bromine-Radical-Mediated Selective Alkylation and Amination of Unactivated C(sp3)–H Bonds

Jia, Penghao,Li, Qingyao,Poh, Wei Chuen,Jiang, Heming,Liu, Haiwang,Deng, Hongping,Wu, Jie

, p. 1766 - 1776 (2020)

C–H functionalization has provided new opportunities to construct organic molecules in an atom- and step-economic manner, facilitating the derivatization of complex pharmaceutical compounds. However, because of the intrinsically high bond dissociation ene

Bromination of organic molecules with polymer-supported bromine complexes

Zupan,Segatin

, p. 2617 - 2626 (1994)

Three types of bromine complexes with various polymers bearing basic units (pyridine, piperidine and piperazine) were investigated and the role of polymer matrices on reactivity was tested by three types of organic reactions: electrophilic addition, aroma

A perpendicular phenyl-induced exceedingly efficient solid-state excited state intramolecular proton transfer fluorophore based on 2-(2-hydroxyphenyl)benzothiazole

Wang, Qin,Xu, Longfei,Niu, Yahui,Wang, Yuxiu,Yuan, Mao-Sen,Zhang, Yanrong

, p. 365 - 370 (2017)

Fluorescent solid-state organic materials have been intensively researched in recent years. In this study, two 2-(2-hydroxyphenyl)benzothiazole (HBT) derivatives: phenylethylene-modified HBT (HBT-s-Ph) and diphenylethylene-modified HBT (HBT-d-Ph), were sy

Dibrominated addition and substitution of alkenes catalyzed by Mn2(CO)10

Chan, Albert S. C.,Jiang, Yi,Meng, Shanshui,Song, Xianheng,Zhang, Hong,Zou, Yong

supporting information, p. 13385 - 13388 (2021/12/17)

A practical method for the dibromination of alkenes without using molecular bromine is consistently appealing in organic synthesis. Herein, we report Mn-catalyzed dibrominated addition and substitution of alkenes only with N-bromosuccinimide, producing a variety of synthetically valuable dibrominated compounds in moderate to high yields. This journal is

Bromination of 1,1-diarylethylenes with bromoethane

Yu, Ze,Jiang, Jialiang,Chen, Hongtai,Tang, Xiangyang

supporting information, p. 2544 - 2552 (2021/07/06)

Aliphatic bromide was used as a halogenation reagent in the presence of DMSO, resulting in 2,2-diarylvinyl bromides from the corresponding 1,1-diarylethylenes. This protocol not only provides a convenient and straightforward strategy for the rapid construction of various 2,2-diarylvinyl bromides without bromine and extra oxidants, but also can improve the atom economy of Kornblum oxidative reaction.

Visible light-mediated metal-free double bond deuteration of substituted phenylalkenes

Iakovenko, Roman,Hlavá?, Jan

supporting information, p. 440 - 446 (2021/01/28)

Various bromophenylalkenes were reductively photodebrominated by using 1,3-dimethyl-2-phenyl-1H-benzo-[d]imidazoline (DMBI) and 9,10-dicyanoanthracene. With deuterated DMBI analogs (the most effective was DMBI-d11), satisfactory to excellent isotopic yields were obtained. DMBI-d11 could also be regenerated from the reaction mixtures with a recovery rate of up to 50%. The combination of the photodebromination reaction with conventional methods for bromoalkene synthesis enables sequential monodeuteration of a double bond without the necessity of a metal catalyst. This journal is

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