The preparations and properties of tris(perfluoroorgano)bismuth compounds Bi(Rf)3 (Rf=CF3, C2F5, n-C3F7, n-C4F9, n-C6F13, n-C8H17, C6F5)

Article abstract of DOI:10.1016/0022-328X(87)80094-3

Tris(perfluoroorgano)bismuth compounds Bi(R_f)3 (R_f=CF3, C2F5, n-C3F7, n-C4F9, n-C6H13, n-C8H17, C6F5) are easily prepared in high yields from the reactions of perfluoroorganocadmium complexes with BiCl3 or BiBr3 in aprotic solvents.T