461-08-5

Basic information

• Product Name: HELIOTROPYL ISO-BUTYRATE
• Synonyms: HELIOTROPYL ISO-BUTYRATE;Carbonotrithioic acid bis(trifluoromethyl) ester;Trithiocarbonic acid bis(trifluoromethyl) ester
• CAS NO: 461-08-5
• Molecular Formula: C₃F₆S₃
• Molecular Weight: 246.22
• Mol File: 461-08-5.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 87.4°Cat760mmHg
• Flash Point: 6.6°C
• Appearance: /
• Density: 1.712g/cm³
• Vapor Pressure: 71.9mmHg at 25°C
• Refractive Index: 1.47
• CAS DataBase Reference: HELIOTROPYL ISO-BUTYRATE(CAS DataBase Reference)
• NIST Chemistry Reference: HELIOTROPYL ISO-BUTYRATE(461-08-5)
• EPA Substance Registry System: HELIOTROPYL ISO-BUTYRATE(461-08-5)

Safety Data

• Hazardous Substances Data: 461-08-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C3F6S3/c4-2(5,6)11-1(10)12-3(7,8)9

Upstream product

• 7789-23-3 potassium fluoride 
• 1495-18-7 fluorothiocarbonyl chloride 
• 7783-39-3 mercury(II) fluoride 
• 753-94-6 trifluoro methyl silyl sulfide 
• 330660-35-0 silver cyanide 
• 21259-75-6 mercury bis(trifluoromethanethiolate) 
• 7439-92-1 lead 
• 55860-39-4 trifluoromethyldisulfane 
• 13400-13-0 cesium fluoride 
• 681-87-8 tetrakis(trifluoromethylmercapto)methane 
• 98-07-7 Benzotrichlorid 
• 3872-23-9 Copper(I) trifluoromethanethiolate 
• 353-55-9 dibromochlorofluoromethane 
• 593-89-5 methyldichloroarsane 

Downstream Products

• 182684-88-4 N-Pentafluorophenyl(C-pentafluorophenyl)imidoyl fluoride 
• 19364-92-2 2,3,4,5,6-pentafluoro-N-(pentafluorophenyl)benzamide 
• 371-78-8 bis-(trifluoromethyl)sulfide 
• 372-64-5 Bis(trifluoromethyl)disulfid 
• 691-69-0 tris(trifluoromethylthio)methane 
• 13003-40-2 tetrakis(trifluoromethylsulfanyl)ethylene 
• 62872-38-2 hexakis(trifluoromethylsulfanyl)ethane 
• 59529-76-9 1-[(trifluoromethyl)thio]hexane 
• 7664-39-3 hydrogen fluoride 
• 7783-06-4 hydrogen sulfide 
• 373-80-8 trifluoromethyl sulfur pentafluoride 
• 1493-15-8 trifluoromethylsulfide 
• 75-15-0 carbon disulfide 
• 78840-55-8 1-Trifluoromethylsulfanyl-heptane 

Relevant articles and documents

Reactions of trifluoromethylthiocopper with halomethanes

The reaction of trifluoromethylthiocopper with halomethanes, namely di-and triiodo-, dibromodichloro-, dibromochlorofluoro-, dibromo-difluoro-, bromochlorofluoro-, phenyltrichloro-, bromocyano-and dibromofluoro-methanes, has been investigated in detail. In addition to the expected compounds, the formation of unusual products such as bis (trifluoromethyl) trithiocarbonate, dimethyl (trifluoromethylthio) benzene, bis (trifluoromethylthio) fluoromethane, (trifluoromethylthio) carbonyl fluoride, carbon disulfide, carbon tetrachloride, trifluoromethylthio-benzoate, etc. was observed. In some cases, bis (trifluoromethylthio) mercury has been used instead of trifluoromethylthiocopper. The mechanism of formation of the various products and their mass spectral fragmentation behavior are described.