358-15-6Relevant academic research and scientific papers
Oxidation Reactions with HOF and Adducts of HOF and HF with Acetonitrile
Dunkelberg, Oliver,Haas, Alois,Klapdor, Martin Frank,Mootz, Dietrich,Poll, Wolfgang,Appelman, Evan Hugh
, p. 1871 - 1876 (2007/10/02)
In acetonitrile solution HOF oxides CF3SSCF3 via CF3S(O)nSCF3 (N = 1, 2) to yield 2O.Analogously, CF3Se(O)OH and CF3SeX (X = Cl, Br) are oxidized via CF3Se(VI) intermediates to provide finally 2O.With CH3CN at low temperatures HOF and HF for 1:1 adducts, whose structures have been elucidated by low-temperature X-ray structure analysis.Additional proof for the formation of CH3CN*HF in the liquid phase is provided. - Key Words: Oxidation by HOF / Hypofluorous acid / Addition compounds of HOF and HF with acetonitrile
Chemistry of trifluoromethylsulfinyl fluoride. Trifluoromethylsulfinamides and trifluoromethylsulfinate esters
Sauer, Dennis T.,Shreeve, Jean'ne M.
, p. 358 - 362 (2007/10/12)
Trifluoromethylsulfinate esters and trifluoromethylsulfinamides result when trifluoromethylsulfinyl fluoride reacts with alcohols and amines. Mercaptans with CF3S(O)F do not yield the expected thiosulfinates but rather mixed disulfides. The methylene protons of CF3CH2OS(O)CF3 and CH3CH2OS(O)CF3 are magnetically nonequivalent giving rise to ABM3X3 nmr spectra. The new compounds CF3S(O)OCH3, CF3S(O)OCH2CH3, CF3S(O)OCH2CF3, CF3S(O)N(CH2CH3)2, CF3S(O)N(CH3)2, (CF3S(O))2NCH3, and CF3S(O)NH2 are slightly volatile, colorless liquids.
