36195-56-9

Basic information

• Product Name: [(2E)-but-2-en-1-ylsulfanyl]benzene
• Synonyms: trans-1-(Phenylthio)-2-butene
• CAS NO: 36195-56-9
• Molecular Formula: C₁₀H₁₂S
• Molecular Weight: 164.2673
• Mol File: 36195-56-9.mol
• Article Data: 24

Chemical Properties

• Boiling Point: 231.5°C at 760 mmHg
• Flash Point: 92.4°C
• Density: 1g/cm³
• Vapor Pressure: 0.0941mmHg at 25°C
• Refractive Index: 1.565
• CAS DataBase Reference: [(2E)-but-2-en-1-ylsulfanyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(2E)-but-2-en-1-ylsulfanyl]benzene(36195-56-9)
• EPA Substance Registry System: [(2E)-but-2-en-1-ylsulfanyl]benzene(36195-56-9)

Safety Data

• Hazardous Substances Data: 36195-56-9(Hazardous Substances Data)

Upstream product

• 21106-26-3 trans-1-Phenylmercaptobuten-⁽¹⁾ 
• 108-98-5 thiophenol 
• 591-97-9 1-chloro-2-butene 
• 4784-77-4 (E/Z)-crotyl bromide 
• 591-51-5 phenyllithium 
• 103185-13-3 (E)-crotyl methyl carbonate 
• 930-69-8 sodium thiophenolate 
• 6117-91-5 (E/Z)-2-buten-1-ol 
• 563-52-0 2-chloro-3-butene 
• 4894-61-5 trans-but-2-enyl chloride 
• 591-50-4 iodobenzene 
• 188400-13-7 S-(E)-crotyl N-methylthiocarbamate 
• 4784-77-4 (E)-1-Bromo-2-butene 
• 106-99-0 buta-1,3-diene 

Downstream Products

• 134427-72-8 ethyl 3-methyl-2-(phenylthio)-2-(trifluoromethyl)-4-pentenoate 
• 35802-48-3 (1-methyl-2-propenyl)dimethylphenylsilane 
• 106070-43-3 ((E)-But-2-enyl)-dimethyl-phenyl-silane 
• 138223-98-0 bis(methoxymethyl) ether of 2,3-dihydro-5,7-dihydroxy-2-<1-(2-phenylthio-3-pentenyl)>benzofuran 
• 138224-02-9 5,7-Bis-(1-ethoxy-ethoxy)-2-((E)-2-phenylsulfanyl-pent-3-enyl)-2,3-dihydro-benzofuran 
• 21106-26-3 trans-1-Phenylmercaptobuten-⁽¹⁾ 
• 72863-24-2 (E)-(but-2-en-1-ylsulfonyl)benzene 
• 86838-05-3 γ-methylallyl phenyl sulphoxide 
• 36195-55-8 (Z)-but-2-en-1-yl phenyl sulfide 
• 3708-35-8 Ethyl 2-(ethoxycarbonyl)-5-phenyl-4-pentenoate 
• 72335-26-3 Ethyl-(1-phenyl)-allylmalonat 
• 108691-90-3 syn-(μ-η3-1-methylallyl)(μ-benzenethiolato)bis(tricyclohexylphosphine)dipalladium(I) 
• 83248-82-2 (E)-9-(phenylsulfinyl)-10-dodecen-1-ol 
• 110363-49-0 5-hexyl-4-methyl-2-phenylthiofuran 

Relevant articles and documents

Direct oxidative allylic and vinylic amination of alkenes through selenium catalysis

Bringing "N" into the game: The direct chemoselective nitrogenation of unactivated alkenes can be achieved through oxidative selenium catalysis (see scheme). This method provides a broad variety of allylic imides in yields of up to 89 % using N-fluorobenzenesulfonimide (NFSI) as the terminal oxidant and nitrogen source. Furthermore, an unprecedented selenium-catalyzed vinylic C(sp2)-H nitrogenation was discovered. Copyright

Silica nanoparticles as a reusable catalyst: A straightforward route for the synthesis of thioethers, thioesters, vinyl thioethers and thio-Michael adducts under neutral reaction conditions

A simple and straightforward route for the synthesis of thioethers, thioesters, vinyl thioethers and thio-Michael adducts has been demonstrated using silica nanoparticles (NPs) as a reusable catalyst via the 1,2-addition of thiols to alkenes, alkynes and alkyl/acyl halides, and the 1,4-addition of thiols to conjugated alkenes at room temperature.

Ionic liquid as catalyst and reaction medium: A simple, convenient and green procedure for the synthesis of thioethers, thioesters and dithianes using an inexpensive ionic liquid, [pmIm]Br

An easily accessible and inexpensive room temperature ionic liquid, 1-pentyl-3-methylimidazolium bromide, [pmIm]Br efficiently catalyzes the reaction of alkyl halides or acyl halides with thiols without any solvent at room temperature leading to the synthesis of thioethers and thioesters in high yields. This reaction has also been extended for the preparation of dithianes and transthioetherification. The ionic liquid is recovered and recycled for subsequent runs.