3723-23-7Relevant articles and documents
Oae,Furukawa
, p. 62,63 (1965)
Carbon Dioxide. A Reagent for the Protection of Nucleophilic Centers and the Simultaneous Activation for Electrophilic Attack. Part 4. The α-Substitution of (i) Benzyl Alcohol and (ii) Benzylamine
Katritzky, Alan R.,Fan, Wei-Qiang,Akutagawa, Kunihiko
, p. 415 - 418 (2007/10/02)
Benzyl alcohol is converted into a variety of α-substituted derivatives by a one-pot sequence involving lithiation of an intermediate hemicarbonate ester.Benzylamine is similarly converted by a one-pot sequence to α-substituted benzylamines: here an intermediate carbamate salt is involved.