574-15-2Relevant articles and documents
Imidazole oxime ester compound, preparation method, composition and use thereof (by machine translation)
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Paragraph 0039-0042, (2019/05/11)
The invention relates to novel imidazole oxime ester compound, preparation method, composition and in photoinitiators, photosensitizers, the light absorbent, or sensitizers of the application. The invention imidazole oxime ester compound, at the same time with imidazole kind of light initiator (for example BCIM) and oxime mere initiator (for example 0 XE - 1) structural features. In one aspect, the compounds of the invention has improved the imidazole kind of light will produce sludge to the shortcoming of the initiator. On the other hand, compound of the present invention improved the thermal stability of the oxime [...] initiator problem not good, and increasing the operating convenience. (by machine translation)
Discovery of a series of ruthenium(II) derivatives with α-dicarbonylmonoxime as novel inhibitors of cancer cells invasion and metastasis
He, Yihui,Xue, Huiying,Zhang, Wendian,Wang, Li,Xiang, Guangya,Li, Lei,Shang, Xianmei
, p. 82 - 92 (2017/05/19)
A series of novel ruthenium(II)-cymene complexes (1–9) with substituted α-dicarbonylmonoximes of general formula [Ru(η6-cymene)(L)Cl] (L?=?N,O-chelating bidentate α-dicarbonylmonoxime derivatives) have been synthesized and characterized by elemental analysis, IR, 1H NMR, 13C NMR spectroscopies, and in three cases by single crystal X-ray diffraction analysis. The most effective compound 9 displays remarkable anti-invasion and anti-metastasis properties without apparent cytotoxicity toward three different human cancer cell lines (MCF-7, Hela and HepG2). Further protein level studies suggest that the anti-metastasis activity of the complexes may result from the increasing expression of E-cadherin and reducing expression of Vimentin.
Synthesis of oximes with NH2OH.HCl/DOWEX(R)50WX4 system
Setamdideh, Davood,Khezri, Behrooz,Esmaeilzadeh, Seyran
, p. 1119 - 1124 (2012/10/30)
The oximation of a variety of carbonyl compounds was efficiently carried out with DOWEX(R)50WX4/NH2OH·HCl system. The reactions were performed in ethanol to give Z-aldoximation isomers of aldehydes and E-oximaton of acetophenone derivatives in a perfect selectively. The oximation of compounds with two carbonyl groups was carried out selectively on one carbonyl moiety. Also, the oximation of aldehydes over ketones has been accomplished successfully by this system.